Full Text:   <2654>

CLC number: TB301

On-line Access: 2013-12-03

Received: 2013-07-15

Revision Accepted: 2013-10-23

Crosschecked: 2013-11-07

Cited: 0

Clicked: 5341

Citations:  Bibtex RefMan EndNote GB/T7714

-   Go to

Article info.
Open peer comments

Journal of Zhejiang University SCIENCE A 2013 Vol.14 No.12 P.898-905

http://doi.org/10.1631/jzus.A1300246


Coating behavior and surface hardening of Pd77Cu6Si17 thin film metallic glass on AZ31 magnesium alloy*


Author(s):  X.H. Du1,2, Y.C. Chang2, H.J. Pei2, B.Y. Chen2, M.C. Kuo3, J.C. Huang2

Affiliation(s):  1. School of Materials Sciences and Engineering, Shenyang Aerospace University, Shenyang 110034, China; more

Corresponding email(s):   602@imr.ac.cn

Key Words:  Thin film metallic glass (TFMG), Magnesium alloy, Sputtering process, Nanoindentation, Coating thickness


X.H. Du, Y.C. Chang, H.J. Pei, B.Y. Chen, M.C. Kuo, J.C. Huang. Coating behavior and surface hardening of Pd77Cu6Si17 thin film metallic glass on AZ31 magnesium alloy[J]. Journal of Zhejiang University Science A, 2013, 14(12): 898-905.

@article{title="Coating behavior and surface hardening of Pd77Cu6Si17 thin film metallic glass on AZ31 magnesium alloy",
author="X.H. Du, Y.C. Chang, H.J. Pei, B.Y. Chen, M.C. Kuo, J.C. Huang",
journal="Journal of Zhejiang University Science A",
volume="14",
number="12",
pages="898-905",
year="2013",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A1300246"
}

%0 Journal Article
%T Coating behavior and surface hardening of Pd77Cu6Si17 thin film metallic glass on AZ31 magnesium alloy
%A X.H. Du
%A Y.C. Chang
%A H.J. Pei
%A B.Y. Chen
%A M.C. Kuo
%A J.C. Huang
%J Journal of Zhejiang University SCIENCE A
%V 14
%N 12
%P 898-905
%@ 1673-565X
%D 2013
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A1300246

TY - JOUR
T1 - Coating behavior and surface hardening of Pd77Cu6Si17 thin film metallic glass on AZ31 magnesium alloy
A1 - X.H. Du
A1 - Y.C. Chang
A1 - H.J. Pei
A1 - B.Y. Chen
A1 - M.C. Kuo
A1 - J.C. Huang
J0 - Journal of Zhejiang University Science A
VL - 14
IS - 12
SP - 898
EP - 905
%@ 1673-565X
Y1 - 2013
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.A1300246


Abstract: 
Pd77Cu6Si17 (PCS) thin film metallic glasses (TFMGs) with high glass forming ability and hardness were selected as a hard coating for improving the surface hardness of AZ31 magnesium alloy. Both microindentation and nanoindentation tests were conducted on specimens with various PCS film thicknesses from 30 to 2000 nm. The apparent hardness and the relative indentation depth (β) were integrated using a quantitative model. The interaction parameters involved and relative hardness values were extracted from iterative calculations. According to the results, surface hardness can be enhanced greatly by PCS TFMGs in the shallow region, followed by gradual decrease with increasing β ratio. In addition, specimens with thinner coatings (e.g., 200 nm) showed greater substrate-film interaction and those with thick coatings (e.g., 2000 nm) became prone to film cracking. The optimum TFMG coating thickness in this study was estimated to be around 200 nm.

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

References

[1] Ahn, J.H., Kwon, D., 2000. Micromechanical estimation of composite hardness using nanoindentation technique for thin-film coated system. Materials Science and Engineering: A, 285(1-2):172-179. 


[2] Chou, H.S., Du, X.H., Lee, C.J., Huang, J.C., 2011. Enhanced mechanical properties of multilayered micropillars of amorphous ZrCuTi and nanocrystalline Ta layers. Intermetallics, 19(7):1047-1051. 


[3] Chu, J.P., Liu, C.T., Mahalingam, T., Wang, S.F., OKeefe, M.J., Johnson, B., Kuo, C.H., 2004. Annealing-induced full amorphization in a multicomponent metallic film. Physical Review B: Condensed Matter and Materials Physics, 69(11):113410


[4] Ferkel, H., Mordike, B.L., 2001. Magnesium strengthened by SiC nanoparticles. Materials Science and Engineering: A, 298(1-2):193-199. 


[5] Gray, J.E., Luan, B., 2002. Protective coatings on magnesium and its alloys—a critical review. Journal of Alloys and Compounds, 336(1-2):88-113. 


[6] Hata, S., Sato, K., Shimokohbe, A., 1999. Fabrication of Thin Film Metallic Glass and Its Application to Microactuators. , Proc. SPIE 3892, Device and Process Technologies for MEMS and Microelectronics, Gold Coast, Australia, :


[7] Hata, S., Liu, Y.D., Wada, K., Shimokohbe, A., 2001. Fabrication of thin film metallic glasses and their properties. Journal of the Japan Society for Precision Engineering, (in Japanese),67(10):1708-1713. 


[8] Inoue, A., 2000. Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Materialia, 48(1):279-306. 

[9] Inoue, A., Kato, A., Zhang, T., Kim, S.G., Masumoto, T., 1991. Mg-Cu-Y amorphous alloys with high mechanical strengths produced by a metallic mold casting method. Materials Transactions, JIM, 32(7):609-616. 

[10] Inoue, A., Shen, B.L., Koshiba, H., Kato, H., Yavari, A.R., 2003. Cobalt-based bulk glassy alloy with ultrahigh strength and soft magnetic properties. Nature Materials, 2(10):661-663. 


[11] Johnson, W.L., 1998. Bulk Glass-forming Metallic Alloys: Science and Technology [1998 Mrs Medal Award Lecture, Presented at Symposium Mm]. MRS Proceedings, 554, 311,:


[12] Kojima, Y., 2000. Platform science and technology for advanced magnesium alloys. Materials Science Forum, 350-351(3):3-18. 


[13] Korsunsky, A.M., McGurk, M.R., Bull, S.J., Page, T.F., 1998. On the hardness of coated systems. Surface and Coatings Technology, 99(1-2):171-183. 


[14] Kuan, S.Y., Chou, H.S., Liu, M.C., Du, X.H., Huang, J.C., 2010. Micromechanical response for the amorphous/amorphous nanolaminates. Intermetallics, 18(12):2453-2457. 


[15] Liu, M.C., Huang, J.C., Chou, H.S., Lai, Y.H., Lee, C.J., Nieh, T.G., 2009. A nanoscaled underlayer confinement approach for achieving extraordinarily plastic amorphous thin film. Scripta Materialia, 61(8):840-843. 


[16] Liu, M.C., Lee, C.J., Lai, Y.H., Huang, J.C., 2010. Microscale deformation behavior of amorphous/nanocrystalline multilayered pillars. Thin Solid films, 518(24):7295-7299. 


[17] Navinsek, B., Panjan, P., Kruič, J., 1998. Hard coatings on soft metallic substrates. Surface and Coatings Technology, 98(1-3):809-815. 


[18] Pang, S.J., Zhang, T., Asami, K., Inoue, A., 2001. New Fe-Cr-Mo-(Nb, Ta)-C-B glassy alloys with high glass-forming ability and good corrosion resistance. Materials Transactions, JIM, 42(2):376-379. 


[19] Pei, H.J., Lee, C.J., Du, X.H., Chang, Y.C., Huang, J.C., 2011. Tension behavior of metallic glass coating on Cu foil. Materials Science and Engineering: A, 528(24):7317-7322. 


[20] Tuck, J.R., Korsunsky, A.M., Bhat, D.G., Bull, S.J., 2001. Indentation hardness evaluation of cathodic are deposited thin hard coatings. Surface and Coatings Technology, 139(1):63-74. 


[21] Wang, W.H., Dong, C., Shek, C.H., 2004. Bulk metallic glasses. Materials Science and Engineering: R: Reports, 44(2-3):45-89. 


[22] Yao, K.F., Yang, Y.Q., Chen, N., 2007. Mechanical properties of Pd-Cu-Si bulk metallic glass. Intermetallics, 15(5-6):639-643. 



Open peer comments: Debate/Discuss/Question/Opinion

<1>

Please provide your name, email address and a comment





Journal of Zhejiang University-SCIENCE, 38 Zheda Road, Hangzhou 310027, China
Tel: +86-571-87952783; E-mail: cjzhang@zju.edu.cn
Copyright © 2000 - 2024 Journal of Zhejiang University-SCIENCE