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Journal of Zhejiang University SCIENCE A

ISSN 1673-565X(Print), 1862-1775(Online), Monthly

In-situ synthesis and luminescence properties of titanium oxide gels containing 1,10-phenanthroline europium(III) complex

Abstract: It is difficult to directly dope europium complexes in gel because the excessive water or high acidic condition may lead to their decomposition. We prepared a novel homogeneous TiO2 gel containing Eu-phen complexes by using an in-situ synthesis method. The formation of Eu-phen complexes in sol-gel derived TiO2 was confirmed by luminescence excitation spectra. The effects of temperature and aging time on in-situ synthesis are discussed. The luminescence spectra of gel containing europium complexes were also compared with the pure Eu-phen complexes.

Key words: In-situ synthesis, Europium complex, Titanium dioxide gel, Luminescence


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DOI:

10.1631/jzus.2005.A0619

CLC number:

O614. 33

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Received:

2005-01-23

Revision Accepted:

2005-04-08

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