Abstract: Photochemical reactions of poly(3-butoxythiophene-2,5-diyl) with chloroform under irradiation with light were studied. The reactions were separately carried out under air, oxygen, and nitrogen. The obtained results showed that this reaction belongs to the pseudo-first-order reaction with a rate constant k_obs of 1.4×10⁻⁵ s⁻¹ at room temperature. The presence or absence of air, oxygen, and nitrogen did not have obvious effects on the reaction rate under irradiation with light.

Key words: Poly(3-butoxythiophene-2,5-diyl), Photochemical reaction, Kinetics

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