Abstract: Composite materials of Fe/Al₂O₃, which consist of small particles of iron supported by thermally stable alumina even at 500–700 °C, have been widely used in the water-gas shift reaction for natural gas reforming. Therefore, Fe/Al₂O₃ is one of the promising candidates for re-transformation of exhausted CO₂ into fuels such as alcohols and hydrocarbons. The development of a CO₂ reforming system using the composite materials of Fe/Al₂O₃ through CO₂ reduction to CO, dissociation of water into hydrogen, and methanol synthesis has been investigated. It was found that dry and steam (i.e. wet) reforming of CO₂ produced almost the same amount of CO. At a temperature above 500 °C, maximal and saturated yields of CO and H₂ from CO₂ and water were obtained. However, this CO₂ reforming system requires higher-pressure conditions from several tens to hundreds standard atmospheric pressure in order to achieve high yield and selectivity for methanol production. In this study we developed the modified CO₂ reforming system by the utilization of Ni and/or Cu instead of Fe in order to obtain other types of useful products such as CO, CH₄, and carbon, more efficiently and selectively under atmospheric pressure. When Ni or Cu was used, conversion of CO₂ was reduced to 76%, while 9% of methane was detected in the case of Ni. On the other hand, though the CO₂ conversion reduced half of the Fe, the selectivity of CO from CO₂ increased to 95% in the case of Cu.

Key words: Iron catalyst; CO₂ reduction; Water-gas shift reaction; Methanol synthesis

Please provide your name, email address and a comment

Your Name: Affili: E-Mail Address:

Comment (Please comment in English):


Verification Code(click to change a pic):