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Journal of Zhejiang University SCIENCE A

ISSN 1673-565X(Print), 1862-1775(Online), Monthly

NiCo2O4 nanoparticles: an efficient and magnetic catalyst for Knoevenagel condensation

Abstract: The Knoevenagel condensation reaction has wide applications ranging from the manufacture of basic chemicals to pharmaceutical intermediates. In this study, we developed an efficient and magnetic bimetallic NiCo2O4 nanocatalyst by coprecipitation. When used in the Knoevenagel condensation between various benzaldehydes and malononitrile, the catalyst exhibited excellent catalytic performance with 99% conversion and 99% selectivity under mild conditions. It can be easily recovered with a magnet and recycled for 20 runs without significant loss of activity. We expect that the catalyst will find large-scale industrial applications.

Key words: NiCo2O4 catalyst; Spinel; Knoevenagel condensation; Heterogeneous catalysis

Chinese Summary  <112> 高效的磁性NiCo2O4纳米粒子催化脑文格尔缩合反应的研究

关键词组:NiCo2O4催化剂; 尖晶石; 脑文格尔缩合反应; 非均相催化


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DOI:

10.1631/jzus.A1900535

CLC number:

TQ138.1

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On-line Access:

2020-01-04

Received:

2019-10-22

Revision Accepted:

2019-12-12

Crosschecked:

2019-12-28

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