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CLC number: TQ150.9; X783
On-line Access: 2024-08-27
Received: 2023-10-17
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Study on US/O3 mechanism in p-chlorophenol decomposition
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XU Xian-wen, XU Xin-hua, SHI Hui-xiang, WANG Da-hui. Study on US/O3 mechanism in p-chlorophenol decomposition[J]. Journal of Zhejiang University Science B, 2005, 6(6): 553-558.
@article{title="Study on US/O3 mechanism in p-chlorophenol decomposition",
author="XU Xian-wen, XU Xin-hua, SHI Hui-xiang, WANG Da-hui",
journal="Journal of Zhejiang University Science B",
volume="6",
number="6",
pages="553-558",
year="2005",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.2005.B0553"
}
%0 Journal Article
%T Study on US/O3 mechanism in p-chlorophenol decomposition
%A XU Xian-wen
%A XU Xin-hua
%A SHI Hui-xiang
%A WANG Da-hui
%J Journal of Zhejiang University SCIENCE B
%V 6
%N 6
%P 553-558
%@ 1673-1581
%D 2005
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.2005.B0553
TY - JOUR
T1 - Study on US/O3 mechanism in p-chlorophenol decomposition
A1 - XU Xian-wen
A1 - XU Xin-hua
A1 - SHI Hui-xiang
A1 - WANG Da-hui
J0 - Journal of Zhejiang University Science B
VL - 6
IS - 6
SP - 553
EP - 558
%@ 1673-1581
Y1 - 2005
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.2005.B0553
Abstract: Study on the effects of sonolysis, ozonolysis and US/O3 system on the decomposition of p-chlorophenol in aqueous solutions indicated that in the cases of US/O3 system, individual ozonolysis and sonolysis, the decomposition rate of p-chlorophenol reached 78.78%, 56.20%, 2.79% after a 16-min reaction while its CODcr (chemical oxygen demand) removal rate was 97.02%, 62.17%, 3.67% after a 120-min reaction. The decomposition reaction of p-chlorophenol follows pseudo-first-order kinetics. The enhancement factors of p-chlorophenol and its CODcr under US/O3 system reached 63% and 237% respectively. The main intermediates during the decomposition include catechol, hydroquinone, p-benzoquinone, phenol, fumaric acid, maleic acid, oxalic acid and formic acid. The decomposition mechanism of p-chlorophenol was also discussed.
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