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Kinetics study on biomass pyrolysis for fuel gas production
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CHEN Guan-yi, FANG Meng-xiang, ANDRIES, J., LUO Zhong-yang, SPLIETHOFF, H., CEN Ke-fa. Kinetics study on biomass pyrolysis for fuel gas production[J]. Journal of Zhejiang University Science A, 2003, 4(4): 441-447.
@article{title="Kinetics study on biomass pyrolysis for fuel gas production",
author="CHEN Guan-yi, FANG Meng-xiang, ANDRIES, J., LUO Zhong-yang, SPLIETHOFF, H., CEN Ke-fa",
journal="Journal of Zhejiang University Science A",
volume="4",
number="4",
pages="441-447",
year="2003",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.2003.0441"
}
%0 Journal Article
%T Kinetics study on biomass pyrolysis for fuel gas production
%A CHEN Guan-yi
%A FANG Meng-xiang
%A ANDRIES
%A J.
%A LUO Zhong-yang
%A SPLIETHOFF
%A H.
%A CEN Ke-fa
%J Journal of Zhejiang University SCIENCE A
%V 4
%N 4
%P 441-447
%@ 1869-1951
%D 2003
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.2003.0441
TY - JOUR
T1 - Kinetics study on biomass pyrolysis for fuel gas production
A1 - CHEN Guan-yi
A1 - FANG Meng-xiang
A1 - ANDRIES
A1 - J.
A1 - LUO Zhong-yang
A1 - SPLIETHOFF
A1 - H.
A1 - CEN Ke-fa
J0 - Journal of Zhejiang University Science A
VL - 4
IS - 4
SP - 441
EP - 447
%@ 1869-1951
Y1 - 2003
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.2003.0441
Abstract: Kinetic knowledge is of great importance in achieving good control of the pyrolysis and gasification process and optimising system design. An overall kinetic pyrolysis scheme is therefore addressed here. The kinetic modelling incorporates the following basic steps: the degradation of the virgin biomass materials into primary products (tar, gas and semi-char), the decomposition of primary tar into secondary products and the continuous interaction between primary gas and char. The last step is disregarded completely by models in the literature. Analysis and comparison of predicted results from different kinetic schemes and experimental data on our fixed bed pyrolyser yielded very positive evidence to support our kinetic scheme.
[1]Ahuja, P., Kumar, S. and Singh, P.C., 1996. A model for primary and heterogeneous secondary reactions of wood pyrolysis. Chemical Engineering Technology, 19: 272-281.
[2]Antal, M.J., 1995. Cellulose Pyrolysis kinetics: the current state of knowledge. Ind. Eng. Chem. Res., 34: 703-718.
[3]Anthony, D.B. and Howard, J.B., 1976. Cracking and repolymerization reaction of polymer. AICHEJ., 22:625-634.
[4]Blasi, C.D., 1993. Analysis of conversion and secondary reaction effects within porous solid fuels undergoing pyrolysis. Combustion Science and Technology, 90: 315-340.
[5]Bradbury, A.G.W., Sakai, Y. and Shafizadeh, F.A.,1979. Kinetic model for pyrolysis of cellulose. Journal of Applied Polymerization Science, 23: 3271-3282.
[6]Broido, A. and Nelson, M. A., 1975. Char yield on pyrolysis of cellulose. Combustion and Flame, 24: 263-278.
[7]Chen, G., 1998. Study of mechanism of biomass pyrolysis. Zhejiang University PhD. Thesis (in Chinese).
[8]Curtis, L.J. and Miller, D.J., 1988. Transport model with radiative heat transfer for rapid cellulose pyrolysis. Ind. Eng. Chem. Res., 27:1775-1783.
[9]Font, R., Marcilla, A. and Verdu, E., 1990. Kinetic model of biomass. Ind. Eng. Chem. Res., 29:1846-1957.
[10]Klose, W. and Wiest, W., 1999. Kinetics of pyrolysis of rice husk. Bioresource Technology, 78:53-59.
[11]Koufopanos, C.A., Maschio, G. and Lucchesi, A., 1989. Kinetic modeling of the pyrolysis of biomass and biomass components. The Canadian Journal of Chemical Engineering, 67: 75-84.
[12]Leung, D.Y.C. and Wang, C.L., 1998. Kinetics study of scrap tyre pyrolysis and combustion. Journal of Analytical and Applied Pyrolysis, 45:153-169.
[13]Pyle, D. l. and Zaror, C. A., 1984. Heat transfer and kinetics in the low temperature pyrolysis of solids. Chemical Engineering Science, 39:147-156.
[14]Raveendran, K., Ganesh, A. and Khilar, K.C., 1995. Influence of mineral matter on biomass pyrolysis characteristics. Fuel, 75:1812-1822.
[15]Samolado, M.C. and Vasalos, I.A., 1991. Pyrolysis kinetics of wood. Fuel, 70: 883-889.
[16]Thurner, F. and Mann, U., 1981. Kinetics investigation of wood pyrolysis. Ind. Eng. Chem. Res., 20: 482-489.
[17]Varhegyi, G., Jakab, E. and Antal, M.J., 1994. The broido-shafizadeh model for cellulose pyrolysis true Energy and Fuels, 8: 1345-1351.
[18]Zaror, C. A., Hutching, I.S. and Pyle, D.L.,1988. Secondary char formation in the catalytic pyrolysis of biomass. Fuel, 27: 1775-1789.
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