Full Text:   <2196>

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CLC number: X701

On-line Access: 2017-10-06

Received: 2017-07-10

Revision Accepted: 2017-08-31

Crosschecked: 2017-09-07

Cited: 0

Clicked: 3771

Citations:  Bibtex RefMan EndNote GB/T7714

 ORCID:

Tao Wang

http://orcid.org/0000-0002-0535-7821

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Journal of Zhejiang University SCIENCE A 2017 Vol.18 No.10 P.819-830

http://doi.org/10.1631/jzus.A1700351


Integrated direct air capture and CO2 utilization of gas fertilizer based on moisture swing adsorption


Author(s):  Cheng-long Hou, Yu-song Wu, You-zhou Jiao, Jie Huang, Tao Wang, Meng-xiang Fang, Hui Zhou

Affiliation(s):  State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China; more

Corresponding email(s):   oatgnaw@zju.edu.cn

Key Words:  Direct air capture, Desorption kinetics, Greenhouse, CO2 fertilizer, Cost analysis


Cheng-long Hou, Yu-song Wu, You-zhou Jiao, Jie Huang, Tao Wang, Meng-xiang Fang, Hui Zhou. Integrated direct air capture and CO2 utilization of gas fertilizer based on moisture swing adsorption[J]. Journal of Zhejiang University Science A, 2017, 18(10): 819-830.

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author="Cheng-long Hou, Yu-song Wu, You-zhou Jiao, Jie Huang, Tao Wang, Meng-xiang Fang, Hui Zhou",
journal="Journal of Zhejiang University Science A",
volume="18",
number="10",
pages="819-830",
year="2017",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A1700351"
}

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%T Integrated direct air capture and CO2 utilization of gas fertilizer based on moisture swing adsorption
%A Cheng-long Hou
%A Yu-song Wu
%A You-zhou Jiao
%A Jie Huang
%A Tao Wang
%A Meng-xiang Fang
%A Hui Zhou
%J Journal of Zhejiang University SCIENCE A
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%@ 1673-565X
%D 2017
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A1700351

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T1 - Integrated direct air capture and CO2 utilization of gas fertilizer based on moisture swing adsorption
A1 - Cheng-long Hou
A1 - Yu-song Wu
A1 - You-zhou Jiao
A1 - Jie Huang
A1 - Tao Wang
A1 - Meng-xiang Fang
A1 - Hui Zhou
J0 - Journal of Zhejiang University Science A
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SP - 819
EP - 830
%@ 1673-565X
Y1 - 2017
PB - Zhejiang University Press & Springer
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DOI - 10.1631/jzus.A1700351


Abstract: 
A new concept of low-cost direct air capture technology integrated with a fertilization system is proposed, as an alternative to the application of air derived CO2. A moisture swing sorbent can elevate the CO2 concentration from 400 parts per million (ppm) to several thousand ppm, and this can be used to cultivate plants. Desorption isotherms were determined and are described well by a Langmuir model. The adsorption rate constant and the desorption rate constant were gained at 25 °C, 35 °C, and 45 °C under 1000 ppm concentration of CO2. In accelerated cultivation experiments, the effects of CO2 concentration, light intensity, and spectrum on the CO2 uptake rate of the plants were investigated. A multi-bed desorption system which is capable of providing a continuous and stable CO2 supply for a greenhouse is demonstrated based on the desorption characteristic and CO2 uptake feature of plants. An energy and cost assessment for the integrated system was performed and the results indicated that minimum energy requirements and cost estimate of CO2 are 35.67 kJ/mol and 34.68 USD/t, respectively. This makes direct air capture a competitive and sustainable carbon source for agriculture.

基于变湿吸附的空气CO2捕集与植物利用的耦合研究

目的:探究季铵型聚合物CO2解吸附过程温度和CO2浓度等变量对解吸附热力学和动力学的影响;研究空气CO2捕集供给植物增产的耦合方法,降低空气CO2捕集与利用的能耗与成本。
创新点:1. 基于变湿吸附技术,探究了季铵型聚合物CO2解吸附过程的热力学及动力学特性;2. 获得了CO2作为气肥供给植物增产的关键影响参数; 3. 建立并优化了空气CO2捕集与植物利用的耦合模型。
方法:1. 通过CO2吸附平衡与动力学实验,获得季铵型聚合物CO2解吸附的平衡常数和动力学常数的影响参数;2. 通过植物CO2吸收实验,获得CO2供给植物增产过程中CO2浓度和光照强度对吸收速率的影响;3. 通过理论推导,构建解吸附CO2浓度与吸附剂质量、温度以及吹扫气流量等的关系,获得空气CO2捕集与植物增产的耦合模型并计算CO2捕集的能耗与成本。
结论:1. 季铵型聚合物材料吸附CO2的平衡常数随温度的升高而降低;吸附、解吸附动力学常数随温度的升高而升高。2. CO2供给植物增产的最佳浓度和光照强度为1000 ppm和8000 lux。3. 基于优化的空气捕集与植物利用的耦合算法,CO2的捕集能耗与成本分别为35.67 kJ/mol和34.68 USD/t。

关键词:直接空气捕集;解吸附动力学;温室;CO2气肥;成本分析

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

Reference

[1]APS (American Physical Society), 2011. Direct Air Capture of CO2 with Chemicals: a Technology Assessment for the APS Panel on Public Affairs. APS.

[2]Bandi, A., Specht, M., Weimer, T., et al., 1995. CO2 recycling for hydrogen storage and transportation–electrochemical CO2 removal and fixation. Energy Conversion and Management, 36(6-9):899-902.

[3]Benson, S.M., Orr, F.M., 2008. Carbon dioxide capture and storage. MRS Bulletin, 33(4):303-305.

[4]Brilman, W., Garcia Alba, L., Veneman, R., 2013. Capturing atmospheric CO2 using supported amine sorbents for microalgae cultivation. Biomass and Bioenergy, 53:39-47.

[5]Caton, P.A., Carr, M.A., Kim, S.S., et al., 2010. Energy recovery from waste food by combustion or gasification with the potential for regenerative dehydration: a case study. Energy Conversion and Management, 51(6):1157-1169.

[6]Chiu, S.Y., Kao, C.Y., Chen, C.H., et al., 2008. Reduction of CO2 by a high-density culture of Chlorella sp. in a semicontinuous photobioreactor. Bioresource Technology, 99(9):3389-3396.

[7]Choi, S., Drese, J.H., Eisenberger, P.M., et al., 2011. Application of amine-tethered solid sorbents for direct CO2 capture from the ambient air. Environmental Science & Technology, 45(6):2420-2427.

[8]Dey, S.K., Chutia, R., Das, G., 2012. Oxyanion-encapsulated caged supramolecular frameworks of a tris(urea) receptor: evidence of hydroxide- and fluoride-ion-induced fixation of atmospheric CO2 as a trapped CO32- anion. Inorganic Chemistry, 51(3):1727-1738.

[9]Ferrocino, I., Chitarra, W., Pugliese, M., et al., 2013. Effect of elevated atmospheric CO2 and temperature on disease severity of Fusarium oxysporum f.sp. lactucae on lettuce plants. Applied Soil Ecology, 72:1-6.

[10]Gebald, C., Wurzbacher, J.A., Borgschulte, A., et al., 2014. Single-component and binary CO2 and H2O adsorption of amine-functionalized cellulose. Environmental Science & Technology, 48(4):2497-2504.

[11]Goeppert, A., Czaun, M., May, R.B., et al., 2011. Carbon dioxide capture from the air using a polyamine based regenerable solid adsorbent. Journal of the American Chemical Society, 133(50):20164-20167.

[12]Goldberg, D.S., Lackner, K.S., Han, P., et al., 2013. Co-location of air capture, subseafloor CO2 sequestration, and energy production on the Kerguelen plateau. Environmental Science & Technology, 47(13):7521-7529.

[13]He, H., Li, W., Zhong, M., et al., 2013. Reversible CO2 capture with porous polymers using the humidity swing. Energy & Environmental Science, 6(2):488-493.

[14]Hibberd, J.M., Whitbread, R., Farrar, J.F., 1996. Effect of elevated concentrations of CO2 on infection of barley by Erysiphe graminis. Physiological and Molecular Plant Pathology, 48(1):37-53.

[15]IPCC (Intergovernmental Panel on Climate Change), 2014. Summary for policymakers. In: Climate Change 2014: Mitigation of Climate Change. Working Group III Contribution to the IPCC Fifth Assessment Report. Cambridge University Press, Cambridge, UK.

[16]Khoshnevisan, B., Rafiee, S., Omid, M., et al., 2014. Environmental impact assessment of tomato and cucumber cultivation in greenhouses using life cycle assessment and adaptive neuro-fuzzy inference system. Journal of Cleaner Production, 73:183-192.

[17]Knoope, M.M.J., Guijt, W., Ramirez, A., et al., 2014. Improved cost models for optimizing CO2 pipeline configuration for point-to-point pipelines and simple networks. International Journal of Greenhouse Gas Control, 22: 25-46.

[18]Kong, Y., Shen, X.D., Cui, S., et al., 2015. Facile synthesis of an amine hybrid aerogel with high adsorption efficiency and regenerability for air capture via a solvothermal-assisted sol-gel process and supercritical drying. Green Chemistry, 17(6):3436-3445.

[19]Kothandaraman, J., Goeppert, A., Czaun, M., et al., 2016. Conversion of CO2 from air into methanol using a polyamine and a homogeneous ruthenium catalyst. Journal of the American Chemical Society, 138(3):778-781.

[20]Lackner, K.S., 2009. Capture of carbon dioxide from ambient air. The European Physical Journal Special Topics, 176(1):93-106.

[21]Lackner, K.S., Ziock, H.J., Grimme, P., 1999. Carbon dioxide extraction from air: is it an option? 24th Annual Technical Conference on Coal Utilization & Fuels System.

[22]Lee, W.R., Hwang, S.Y., Ryu, D.W., et al., 2014. Diamine-functionalized metal-organic framework: exceptionally high CO2 capacities from ambient air and flue gas, ultrafast CO2 uptake rate, and adsorption mechanism. Energy & Environmental Science, 7(2):744-751.

[23]Nikulshina, V., Hirsch, D., Mazzotti, M., et al., 2006. CO2 capture from air and co-production of H2 via the Ca(OH)2-CaCO3 cycle using concentrated solar power-thermodynamic analysis. Energy, 31(12):1715-1725.

[24]Pang, S.H., Jue, M.L., Leisen, J., et al., 2015. PIM-1 as a solution-processable “molecular basket” for CO2 capture from dilute sources. ACS Macro Letters, 4(12):1415-1419.

[25]Park, Y.G., Park, J.E., Hwang, S.J., et al., 2013. Light source and CO2 concentration affect growth and anthocyanin content of lettuce under controlled environment. Horticulture, Environment, and Biotechnology, 53(6):460-466.

[26]Poorter, H., 1993. Interspecific variation in the growth-response of plants to an elevated ambient CO2 concentration. Vegetatio, 104(1):77-97.

[27]Qiu, R., Song, J., Du, T., et al., 2013. Response of evapotranspiration and yield to planting density of solar greenhouse grown tomato in northwest China. Agricultural Water Management, 130:44-51.

[28]Runion, G.B., Curl, E.A., Rogers, H.H., et al., 1994. Effects of free-air CO2 enrichment on microbial-populations in the rhizosphere and phyllosphere of cotton. Agricultural and Forest Meteorology, 70(1-4):117-130.

[29]Saha, S., Sehgal, V.K., Chakraborty, D., et al., 2015. Atmospheric carbon dioxide enrichment induced modifications in canopy radiation utilization, growth and yield of chickpea [Cicer arietinum L.)]. Agricultural and Forest Meteorology, 202:102-111.

[30]Schell, J., Casas, N., Blom, R., et al., 2012. MCM-41, MOF and UiO-67/MCM-41 adsorbents for pre-combustion CO2 capture by PSA: adsorption equilibria. Adsorption, 18(3-4):213-227.

[31]Shi, X., Xiao, H., Lackner, K.S., et al., 2016a. Capture CO2 from ambient air using nanoconfined ion hydration. Angewandte Chemie International Edition, 55(12):4026-4029.

[32]Shi, X., Xiao, H., Chen, X., et al., 2016b. The effect of moisture on the hydrolysis of basic salts. Chemistry-A European Journal, 22(51):18326-18330.

[33]Wang, T., Lackner, K.S., Wright, A., 2011. Moisture swing sorbent for carbon dioxide capture from ambient air. Environmental Science & Technology, 45(15):6670-6675.

[34]Wang, T., Lackner, K.S., Wright, A.B., 2013. Moisture-swing sorption for carbon dioxide capture from ambient air: a thermodynamic analysis. Physical Chemistry Chemical Physics, 15(2):504-514.

[35]Wang, T., Huang, J., He, X., et al., 2014. CO2 fertilization system integrated with a low-cost direct air capture technology. Energy Procedia, 63:6842-6851.

[36]Wolff, T., Brinkmann, T., Kerner, M., et al., 2015. CO2 enrichment from flue gas for the cultivation of algae–a field test. Greenhouse Gases: Science and Technology, 5(5):505-512.

[37]Wurzbacher, J.A., Gebald, C., Piatkowski, N., et al., 2012. Concurrent separation of CO2 and H2O from air by a temperature-vacuum swing adsorption/desorption cycle. Environmental Science & Technology, 46(16):9191-9198.

[38]Wurzbacher, J.A., Gebald, C., Brunner, S., et al., 2016. Heat and mass transfer of temperature–vacuum swing desorption for CO2 capture from air. Chemical Engineering Journal, 283:1329-1338.

[39]Xu, S., Zhu, X., Li, C., et al., 2014. Effects of CO2 enrichment on photosynthesis and growth in Gerbera jamesonii. Scientia Horticulturae, 177:77-84.

[40]Zhou, Y.H., Yu, J.Q., Huang, L.F., et al., 2004. The relationship between CO2 assimilation, photosynthetic electron transport and water-water cycle in chill-exposed cucumber leaves under low light and subsequent recovery. Plant, Cell and Environment, 27(12):1503-1514.

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