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Journal of Zhejiang University SCIENCE B 2005 Vol.6 No.1 P.69-73

http://doi.org/10.1631/jzus.2005.B0069


Microcalorimetric study on host-guest complexation of naphtho-15-crown-5 with four ions of alkaline earth metal


Author(s):  SONG Ming-zhi, ZHU Lan-ying, GAO Xi-ke, DOU Jian-min, SUN De-zhi

Affiliation(s):  Department of Chemistry, Liaocheng University, Liaocheng 252059, China

Corresponding email(s):   sundezhisdz@163.com

Key Words:  Microcalorimetry, Host-guest complexation, Naphtho-15-crown-5, Alkaline earth metal, Molecular recognition


SONG Ming-zhi, ZHU Lan-ying, GAO Xi-ke, DOU Jian-min, SUN De-zhi. Microcalorimetric study on host-guest complexation of naphtho-15-crown-5 with four ions of alkaline earth metal[J]. Journal of Zhejiang University Science B, 2005, 6(1): 69-73.

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author="SONG Ming-zhi, ZHU Lan-ying, GAO Xi-ke, DOU Jian-min, SUN De-zhi",
journal="Journal of Zhejiang University Science B",
volume="6",
number="1",
pages="69-73",
year="2005",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.2005.B0069"
}

%0 Journal Article
%T Microcalorimetric study on host-guest complexation of naphtho-15-crown-5 with four ions of alkaline earth metal
%A SONG Ming-zhi
%A ZHU Lan-ying
%A GAO Xi-ke
%A DOU Jian-min
%A SUN De-zhi
%J Journal of Zhejiang University SCIENCE B
%V 6
%N 1
%P 69-73
%@ 1673-1581
%D 2005
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.2005.B0069

TY - JOUR
T1 - Microcalorimetric study on host-guest complexation of naphtho-15-crown-5 with four ions of alkaline earth metal
A1 - SONG Ming-zhi
A1 - ZHU Lan-ying
A1 - GAO Xi-ke
A1 - DOU Jian-min
A1 - SUN De-zhi
J0 - Journal of Zhejiang University Science B
VL - 6
IS - 1
SP - 69
EP - 73
%@ 1673-1581
Y1 - 2005
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.2005.B0069


Abstract: 
Thermodynamic parameters of complexation of naphto-15-crown-5 with four alkaline earth ions in aqueous media was determined using titration microcalorimetry at 298.15 K. The stability of the complexes, thermal effect and entropy effect of the complexation is discussed on the basis of the guest ions structure and the solvent effect. The stability constants tendency to vary with ion radius was interpreted. Complex of naphtha-15-crown-5 with calcium ion is very stable due to the synergism of static electric interaction and size selectivity between the host and the guest.

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

Reference

[1] Alizadeh, N., Shamsipur, M., 1996. Nuclear magnetic resonance study of the legend interchange of Ba2+-18-crown-6 complex in methanol solution. J. Solution Chem., 25(10):1029-1129.

[2] Bai, G., Wang, Y., Yan, H., 2002. Therodynamics of interaction between cationic gemini surfactants and hydrophobically bodified polymers in aqueous solutions. J. Phys. Chem. B, 106(9):2153-2159.

[3] Bryan, J.C., Kavallieratos, K., Sachleben, R.A., 2000. Unusual legend coordination for cesium. Inorg. Chem., 39(7):1568-1572.

[4] Claudia, F.C., Maria, F.S., Tomiyama, C., Brito, H.F., Teotonio, E.E., Malta, O.L., 2003. Synthesis and luminescent properties of supromolecules of diketonate of Eu (III) and crown ethers as ligands. J. Solid State Chemistry, 171(1/2):189-194.

[5] Hamada, T., Manabe, K., Ishikawa, S., Nagayama, S., Shiro, M., Kobayashi, S., 2003. Catalytic asymmetric aldol reactions in aqueous media using chiral bis-pyridino-18-crown-6-rare earth metal triflate complexes. J. Am. Chem. Soc., 125(10):2989.

[6] Huang, Z.Q., 1983. Introduction of Theory about Electrolyte Solution. Science Press, Beijing, China, p.49-60 (in Chinese).

[7] Jensen, M.P., Dzielawa, J.A., Rickert, P., Dietz, M.L., 2002. Exafs investigations of the mechanism of facilitated ion transfer into a room temperature ionic liquid. J. Am. Chem. Soc., 124(36):10664-10668.

[8] Krzysztof, J., Juliusz, S., Luboch, E., 2002. Kinetics of photochromic reactions in a 10-membered dibenzoazo crown ether. Chemical Physics, 285(1):47-54.

[9] Lehn, J.M., 1988. Supramolecular chemistry–Scope and perspectives, molecules, supermolecules, and molecular devices (Nobel Lecture). Chem. Int. Ed. Engl. Angew., 27(1):89-112.

[10] Levitskaia, T.G., Bryan, J.C., Sachleben, R.A., Lamb, J.D., Moyer, B.A., 2000. A surprising host-guest relationship between 1,2-dicloroethane and the cesium complex of tetrobenzo-24-crown-ether. J. Am. Chem. Soc., 122(2):554-562.

[11] Levitskaia, T.G., Sachleben, R.A., Bryan, J.C., Moyer, B.A., 2001. Sythesis, structure, and extraction behavior of 4,5(, 4(,5((-tetra-tert-butytetrabenzo-24-crown-8. J. Chem. Soc., Perkin Trans., 2(5):808-814.

[12] Li, H.P., Wang, P.F., Wu, S.K., 1998. A new flavonecrown ether and its complexation with alkaline and alkaline earth metal cations. Chemical Journal of Chinese Universities, 19(9):1431-1435 (in Chinese).

[13] Lu, X.R., Zhang, L.F., Zhou, X.C., 1994. Polysioxane with pendant benzo crown ether via a spacer of undecyloxymethyl as stationary of capillary chromatography. Chemical Research in Chinese Universities, 10(2):163-166 (in Chinese).

[14] Pedersen, C.J., 1967. Cyclic polyethers and their complexes with metal salts. J. Am. Chem. Soc., 89(26):7017-7036.

[15] Pellet-Rostaing, S., Chitry, F., Lemaire, M., Barnier, H., Federici, V., 1998. Synthesis of water soluble molecular receptor from calyx[4] arene-bis-crown-6. Tetrahedron Lett., 39(51):9443-9446.

[16] Pellet-Rostaing, S., Chitry, F., Nicod, L., Lemaire, M., 2001. Synthesis and complexation properties of 1,3-alternate calyx[4] arene-bis (crown-6) derivatives. J. Chem. Soc., Perkin Trans., 2(8):1426-1432.

[17] Qin, S.Y., 1987. Synthesis of dinaphtho-18-crown-6 and naphtha-15C5. Chemical Reagents (Huaxue Shiji), 9(4):203-204 (in Chinese).

[18] Rahman, M.M., Doe, H., Sakurada, N., Arakawa, R., 2001. Facilitated ion-transfer of alkaline-earth metal cations by naphthao-15-crown-5 across the water. Electrochimica Acta, 47(4):623-631.

[19] Roberta, C., Stefano, D.S., Luigi, M., 2003. The bis-barium complex of a butterfly crown ether as a phototunable supramolecular catalyst. J. Am. Chem. Soc., 125(8):2224-2227.

[20] Shiozuma, M., Takai, Y., Kawamujra, M., Takeda, T., Sawada, M., 2001. Complexation characteristics of permethylated cycloinulohexaose, cycloinuloheptaose, and cycloinuloocttaose with metal cations. J. Chem. Soc., Perkin Trans., 2(8):1306-1314.

[21] Stödeman, M., Wadsö, I., 1995. Scope of microcalorimetry in the area of microcyclic chemistry. Pure & Appl. Chem., 67(7):1059-1068.

[22] Sun, D.Z., Chen, J., Lu, W.M., Zheng, X.M., 1999. Solution thermodynamics of some organic solutes in liquid film of dibenzo-18-crown-6. Indian J. Chem., 38A(11):1195-1199.

[23] Talanova, G.G., Elkarim, N.S.A., Talanov, V.S., Hanes, R.E.Jr., Hwang, H.S., Bartsch, R.A., Rogers, R.D., 1999. The “picrate effect” on extraction selectivities of aromatic group-containing crown ethers for alkali metal cations. J. Am. Chem. Soc., 121(49):11281-11290.

[24] Tanabe, T., Takeshima, M., Mikami, A., 1987. Primary structure of the receptor for calcium channal blockers from skeletal muscle. Nature, 328(1):313-318.

[25] Vijaykumar, S.I., Ashwini, K.S., 2003. Complexation of macrocyclic compounds with mono-, di- and tri-valent transition and heavy metal ions in 90% (v/v) DMSO+water medium. Polyhedron, 22(4):569-574.

[26] Weast, R.C., 19741975. CRC Handbook of Chemistry and Physics, 55th Edition. CRC Press, Ohio, p.F-198.

[27] Wu, C.T., 1992. Chemistry of Crown Ethers. Science Press, Beijing, China, p.114-156 (in Chinese).

[28] Yi, P., Yu, Q., Lin, R., Zong, H., 1997. Coordination reactions of 18-crown-6 with the alkali ions in alcohol solvents. Acta Phys. Chim., 13(6):569-572.

[29] Zbigniew, G., Andrzej, S., Barbara, M.B., 2002. Preparation and decomposition of potassium alkalid-lipophilic crown ether complexes in tetrahydrofuran. J. Org. Chem., 67(22):7807-7812.

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