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Received: 2006-12-21

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Journal of Zhejiang University SCIENCE A 2007 Vol.8 No.7 P.1118-1125

http://doi.org/10.1631/jzus.2007.A1118


Progress and prospect in electro-Fenton process for wastewater treatment


Author(s):  JIANG Cheng-chun, ZHANG Jia-fa

Affiliation(s):  School of Civil and Environmental Engineering, Shenzhen Polytechnic, Shenzhen 518055, China; more

Corresponding email(s):   jiangcc_szpt@126.com

Key Words:  Electro-Fenton, Hydroxyl radicals, Advanced oxidation process (AOP), Refractory wastewater


JIANG Cheng-chun, ZHANG Jia-fa. Progress and prospect in electro-Fenton process for wastewater treatment[J]. Journal of Zhejiang University Science A, 2007, 8(7): 1118-1125.

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author="JIANG Cheng-chun, ZHANG Jia-fa",
journal="Journal of Zhejiang University Science A",
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pages="1118-1125",
year="2007",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.2007.A1118"
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%DOI 10.1631/jzus.2007.A1118

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T1 - Progress and prospect in electro-Fenton process for wastewater treatment
A1 - JIANG Cheng-chun
A1 - ZHANG Jia-fa
J0 - Journal of Zhejiang University Science A
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PB - Zhejiang University Press & Springer
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DOI - 10.1631/jzus.2007.A1118


Abstract: 
As a novel advanced oxidation process (AOP), electro-Fenton process is powerful for degrading most organic compounds including toxic and non-biodegradable ones, and so has attracted great attention. This paper reviews this process in detail including the mechanism, electrolytic bath, electrode materials, aerations and operation parameters. The application of electro-Fenton method in wastewater treatment is evaluated and summarized. Future work in this field is suggested, and three main directions of new electrode exploitation, development of assisted technologies and mechanistic study should be strengthened.

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

Reference

[1] Bellakhal, N., Oturan, M.A., Oturan, N., Dachraoui, M., 2006. Olive oil mill wastewater treatment by the electro-Fenton process. Environ. Chem., 3(5):345-349.

[2] Boye, B., Dieng, M.M., Brillas, E., 2002. Degradation of herbicide 4-chlorophenoxyacetic acid by advanced electrochemical oxidation methods. Environmental Science and Technology, 36(13):3030-3035.

[3] Brillas, E., Casado, J., 2002. Aniline degradation by electro-Fenton and peroxi-coagulation processes using a flow reactor for wastewater treatment. Chemosphere, 47(3):241-248.

[4] Brillas, E., Mur, E., Casado, J., 1996. Iron(II) catalysis of the mineralization of aniline using a carbon-PTFE O2-fed cathode. J. Electrochem. Soc., 143(3):L49-L53.

[5] Brillas, E., Sauleda, R., Casado, J., 1998a. Degradation of 4-chlorophenol by anodic oxidation, electro-Fenton, photoelectro-Fenton, and peroxi-coagulation processes. J. Electrochem. Soc., 145(3):759-765.

[6] Brillas, E., Mur, E., Sauleda, R., Sànchez, L., Peral, J., Domènech, X., Casado, J., 1998b. Aniline mineralization by AOP’s: anodic oxidation, photocatalysis, electro-Fenton and photoelectron-Fenton processes. Appl. Catal. B: Environ., 16(1):31-42.

[7] Brillas, E., Calpe, J.C., Casado, J., 2000. Mineralization of 2,4-D by advanced electrochemical oxidation processes. Water Research, 34(8):2253-2262.

[8] Brillas, E., Boye, B., Sirés, I., Garrido, J.A., Rodríguez, R.M., Arias, C., Cabot, P.L., Comninellis, C., 2004. Electrochemical destruction of cholorophenoxy herbicides by anodic oxidation and electro-Fenton using a boron-doped diamond electrode. Electrochimica Acta, 49(25):4487-4496.

[9] Casado, J., Fornaguera, J., Galán, M.I., 2005. Mineralization of aromatics in water by sunlight-assisted electro-Fenton technology in a pilot reactor. Environmental Science and Technology, 39(6):1843-1847.

[10] Chen, Z., Chen, X., Zheng, X., Chen, R.Y., Lin, Z.H., Chen, Y.F., Zhang, Y.K., 2002. Influence of pH and current concentration on electrochemical-generated hydroxyl radical for degradation and decolorization of dye wastewater. Research of Environmental Sciences, 15:42-52 (in Chinese).

[11] Edelahi, M.C., Oturan, N., Oturan, M.A., Padellec, Y., Bermond, A., Kacemi, K.E., 2003. Degradation of diuron by the electro-Fenton process. Environ. Chem. Lett., 1(4):233-236.

[12] Flox, C., Ammar, S., Arias, C., Brillas, E., Vargas-Zavala, A.V., Abdelhedi, R., 2006. Electro-Fenton and photoelectro-Fenton degradation of indigo carmine in acidic aqueous medium. Appl. Catal. B: Environ., 67(1-2):93-104.

[13] Fockedey, E., Lierde, A.V., 2002. Coupling of anodic and cathodic reactions for phenol electro-oxidation using three-dimensional electrodes. Water Research, 36(16):4169-4175.

[14] Gözmen, B., Oturan, M.A., Oturan, N., Erbatur, O., 2003. Indirect electrochemical treatment of bisphenol A in water via electrochemically generated Fenton’s reagent. Environmental Science and Technology, 37(16):3716-3722.

[15] Guivarch, E., Oturan, N., Oturan, M.A., 2003a. Removal of organophosphorus pesticides from water by electrogenerated Fenton’s reagent. Environ. Chem. Lett., 1(3):165-168.

[16] Guivarch, E., Trevin, S., Lahitte, C., Oturan, M.A., 2003b. Degradation of azo dyes in water by electro-Fenton process. Environ. Chem. Lett., 1(1):38-44.

[17] Han, X., Xia, D., 2004. Study on the treatment of phenol and formaldehyde waste water using Fenton reagent. Sulphur Phosphorus & Bulk Materials Handling Related Engineering, 6:25-28 (in Chinese).

[18] He, C., An, T.C., Xiong, Y., Shu, D., Hu, H.L., Zhu, X.H., 2002. Electrochemical degradation of organic wastwater by three-dimensional electrode reactor. Electrochemistry, 8:327-332 (in Chinese).

[19] Kaichouh, G., Oturan, N., Oturan, M.A., Kacemi, K.E., Hourch, A.E., 2004. Degradation of the herbicide imazapyr by Fenton reactions. Environ. Chem. Lett., 2(1):31-33.

[20] Kusvuran, E., Irmak, S., Yavuz, H.I., Samil, A., Erbatur, O., 2005. Comparison of the treatment methods efficiency for decolorization and mineralization of Reactive Black 5 azo dye. Journal of Hazardous Materials, 119(1-3):109-116.

[21] Lahkimi, A., Oturan, M.A., Oturan, N., Chaouch, M., 2007. Removal of textile dyes from water by the electro-Fenton process. Environ. Chem. Lett., 5(1):35-39.

[22] Oturan, M.A., 2000. An ecologically effective water treatment technique using electrochemically generated hydroxyl radicals for in situ destruction of organic pollutants: Application to herbicide 2,4-D. Journal of Applied Electrochemistry, 30(4):475-482.

[23] Oturan, M.A., Pinson, J., 1995. Hydroxylation by electrochemically generated OH· radicals. Mono- and polyhydroxylation of benzoic acid: products and isomers’ distribution. J. Phy. Chem., 99(38):13948-13954.

[24] Oturan, M.A., Peiroten, J., Chartrin, P., Acher, A.J., 2000. Complete destruction of p-nitrophenol in aqueous medium by electro-Fenton method. Environmental Science and Technology, 34(16):3474-3479.

[25] Oturan, M.A., Oturan, N., Lahitte, C., Trevin, S., 2001. Production of hydroxyl radicals by electrochemically assisted Fenton’s reagent application to the mineralization of an organic micropollutant, pentachlorphenol. Journal of Electroanalytical Chemistry, 507(1-2):96-102.

[26] Pozzo, A.D., Palma, L.D., Merli, C., Petrucci, E., 2005a. An experimental comparison of a graphite electrode and a gas diffusion electrode for the cathodic production of hydrogen peroxide. Journal of Applied Electrochemistry, 35(4):413-419.

[27] Pozzo, A.D., Ferrantelli, P., Merli, C., Petrucci, E., 2005b. Oxidation efficiency in the electro-Fenton process. Journal of Applied Electrochemistry, 35(4):391-398.

[28] Qiang, Z.M., 2002. Removal of Selected Hazardous Organic Compounds by Electro-Fenton Oxidation Process. Ph.D Thesis, Proquest Information and Learning Company, the United States, p.10-20.

[29] Shen, Z.M., Yang, J., Hu, X.F., Lei, Y.M., Ji, X.L., Jia, J.P., Wang, W.H., 2005. Dual electrodes oxidation of dye wastewater with gas diffusion cathode. Environmental Science and Technology, 39(6):1819-1826.

[30] Ventura, A., Jacquet, G., Bermond, A., Camel, V., 2002. Electrochemical generation of the Fenton’s reagent: application to atrazine degradation. Water Research, 36(14):3517-3522.

[31] Wang, A.M., Qu, J.H., Ru, J., Liu, H.J., Ge, J.T., 2005. Mineralization of an azo dye Acid Red 14 by electro-Fenton’s reagent using an activated carbon filber cathode. Dyes and Pigments, 65(3):227-233.

[32] Xiong, Y.J., Fan, J., Zhu, X.H., 1998. Progress and prospect of research in three-dimension electrode. Industrial Water Treatment, 18:5-8 (in Chinese).

[33] Yuan, S.H., Wang, L.L., Lu, X.H., 2004. Studies on the treatment of simulated nitrophenol wastewater by cathode electro-Fenton method. Industrial Water Treatment, 24:33-36 (in Chinese).

[34] Zhang, F., Li, G.M., Zhao, X.H., Hu, H.K., Huang, J.W., 2004. Study status and progress in wastewater treatment by electro-Fenton method. Industrial Water Treatment, 24:9-13 (in Chinese).

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