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On-line Access: 2018-02-05

Received: 2016-10-03

Revision Accepted: 2017-03-16

Crosschecked: 2018-01-15

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Citations:  Bibtex RefMan EndNote GB/T7714


Chang Liu


Jian-guo Yang


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Journal of Zhejiang University SCIENCE A 2018 Vol.19 No.2 P.148-157


Chemical kinetics simulation of semi-dry dechlorination in coal-fired flue gas

Author(s):  Chang Liu, Hong Zhao, Wei-ying Yang, Kun-zan Qiu, Jian-guo Yang, Zi-wen Geng, Wei-ming Teng, Wei-zhong Yuan, Xi-jiong Chen

Affiliation(s):  The State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China; more

Corresponding email(s):   yjg@zju.edu.cn

Key Words:  Coal-fired flue gas, Semi-dry dechlorination, Chemical kinetics, Competition relationship, Na/Cl, CHEMKIN

Chang Liu, Hong Zhao, Wei-ying Yang, Kun-zan Qiu, Jian-guo Yang, Zi-wen Geng, Wei-ming Teng, Wei-zhong Yuan, Xi-jiong Chen. Chemical kinetics simulation of semi-dry dechlorination in coal-fired flue gas[J]. Journal of Zhejiang University Science A, 2018, 19(2): 148-157.

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author="Chang Liu, Hong Zhao, Wei-ying Yang, Kun-zan Qiu, Jian-guo Yang, Zi-wen Geng, Wei-ming Teng, Wei-zhong Yuan, Xi-jiong Chen",
journal="Journal of Zhejiang University Science A",
publisher="Zhejiang University Press & Springer",

%0 Journal Article
%T Chemical kinetics simulation of semi-dry dechlorination in coal-fired flue gas
%A Chang Liu
%A Hong Zhao
%A Wei-ying Yang
%A Kun-zan Qiu
%A Jian-guo Yang
%A Zi-wen Geng
%A Wei-ming Teng
%A Wei-zhong Yuan
%A Xi-jiong Chen
%J Journal of Zhejiang University SCIENCE A
%V 19
%N 2
%P 148-157
%@ 1673-565X
%D 2018
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A1600653

T1 - Chemical kinetics simulation of semi-dry dechlorination in coal-fired flue gas
A1 - Chang Liu
A1 - Hong Zhao
A1 - Wei-ying Yang
A1 - Kun-zan Qiu
A1 - Jian-guo Yang
A1 - Zi-wen Geng
A1 - Wei-ming Teng
A1 - Wei-zhong Yuan
A1 - Xi-jiong Chen
J0 - Journal of Zhejiang University Science A
VL - 19
IS - 2
SP - 148
EP - 157
%@ 1673-565X
Y1 - 2018
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.A1600653

HCl in coal-fired flue gas has adverse impact on the environment, equipment, and the flue gas desulfurization (FGD) system. The existence of HCl also increases the difficulty of the treatment of desulfurization waste water. semi-dry dechlorination technology is put forward to attach chlorine to fly ash by spraying in alkaline solution. Simultaneously, desulphurization waste water is used as the solvent of alkali, and this could help realize the target of near-zero emission of desulfurization waste water. CHEMKIN is used to build a chemical kinetics model, which is based on the measured components of flue gas in a coal-fired power plant. NaOH is set as the alkali absorbent in the model. Both the competitive relationship of SO2 and HCl and the effects of different factors on HCl reaction efficiency are analyzed. SO2 with high concentration would compete for more NaOH, but when na/Cl (ratio in mole) is 1, the reaction efficiency of HCl achieves 22.28%, and it is positively correlated with na/Cl. When na/Cl surpasses 5, the reaction efficiency of HCl increases to beyond 70%. As na/Cl continues to increase, there is a slower growth of HCl reaction efficiency and it finally achieves 100% when na/Cl reaches 12. With a fixed value of na/Cl, a change of 1000 mg/m3 in SO2 concentration would change the reaction efficiency of HCl about 13%. The effect of flue temperature on HCl reaction efficiency is not significant. Acid gases in flue gas react with NaOH completely in 0.1 s and come to equilibrium after about 1 s.


创新点:1. 提出半干法脱氯技术,将氯离子固化到飞灰中; 2. 脱氯后脱硫废水大幅减少,将脱硫废水作为碱基溶剂回喷到烟道中,实现脱硫废水零排放; 3. 建立良搅拌反应器(PSR)模型,探讨半干法脱氯过程的化学动力学反应机理与关键参数.
方法:1. 通过CHEMKIN构建PSR模型,模拟实际燃煤烟气组分下的半干法脱氯过程; 2. 通过敏感性分析,探讨SO2与HCl之间的竞争关系(图8~10); 3. 通过单变量模拟,研究不同因素对反应效率的影响(图13~16).
结论:1. 烟气中的SO2对HCl的脱除存在较大竞争关系,但即使Na/Cl(摩尔比)为1时,HCl的反应效率依然可观. 2. HCl的反应效率与Na/Cl呈正相关;综合考虑反应效率和运行成本,设置Na/Cl为5较为合理. 3. SO2浓度的小范围变化不会对HCl的反应效率造成显著影响. 4. 仅通过化学动力学模拟,烟气温度对HCl的反应效率影响不明显. 5. 烟气中酸性气体与NaOH在0.1 s内即可完成反应,在1 s左右达到平衡.


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