Journal of Zhejiang University SCIENCE A 2026 Vol.27 No.7 P.746-761

http://doi.org/10.1631/jzus.A2500621


Unveiling the drivers of PM2.5 and O3 pollution rebound in Shandong, China during three periods of 2023 by an integrated machine learning method


Author(s):  Gang WANG, Sai LIU, Kai WANG, Huijuan MENG, Na ZHAO, Hanyu ZHANG

Affiliation(s):  1. Department of Environmental and Safety Engineering, College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao 266580, China more

Corresponding email(s):   zhaona2023@sdu.edu.cn, zhy@btbu.edu.cn

Key Words:  Air pollution rebound, Driving factors, Random forest–Shapley additive explanation (RF–SHAP), Anthropogenic emissions, Meteorological conditions


Gang WANG, Sai LIU, Kai WANG, Huijuan MENG, Na ZHAO, Hanyu ZHANG. Unveiling the drivers of PM2.5 and O3 pollution rebound in Shandong, China during three periods of 2023 by an integrated machine learning method[J]. Journal of Zhejiang University Science A, 2026, 27(7): 746-761.

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journal="Journal of Zhejiang University Science A",
volume="27",
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year="2026",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A2500621"
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%T Unveiling the drivers of PM2.5 and O3 pollution rebound in Shandong, China during three periods of 2023 by an integrated machine learning method
%A Gang WANG
%A Sai LIU
%A Kai WANG
%A Huijuan MENG
%A Na ZHAO
%A Hanyu ZHANG
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A1 - Huijuan MENG
A1 - Na ZHAO
A1 - Hanyu ZHANG
J0 - Journal of Zhejiang University Science A
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DOI - 10.1631/jzus.A2500621


Abstract: 
Following the relaxation of coronavirus disease 2019 restrictions and the subsequent full economic recovery, Shandong Province, China experienced a 4.3% rebound in the air quality index in 2023, with both fine particulate matter (PM2.5) and ozone (O3) concentrations exhibiting noticeable upward trends. Quantifying the drivers of this rebound is essential for developing targeted air quality management strategies. To this end, the analysis focused on the early spring period (ESP, February to April) and autumn harvest period (AHP, September to October) for PM2.5 pollution and the photochemical season period (PSP, July to October) for O3 pollution. We developed an interpretable random forest–Shapley additive explanation (RF–SHAP) framework optimized with a tree-structured Parzen estimator (TPE) to assess the impacts of anthropogenic emissions and meteorological factors. The introduction of the TPE optimization technique enhanced RF model performance across these pollution periods. Anthropogenic emissions played the dominant role in PM2.5 pollution rebounds, contributing 14.1% during the ESP and 19.0% during the AHP, for example, industrial recovery (9.2% increase in energy consumption) and agricultural waste burning (70.0% increase in crop residue burning incident). In contrast, O3 pollution was more strongly influenced by meteorological conditions, which contributed a 5.8% increase during the PSP. Critical meteorological drivers included strengthened atmospheric oxidation capacity, reduced total cloud cover, and changes in boundary layer height, although precursor emissions from the transportation and petrochemical industries remained indispensable for O3 formation. This study provides an important scientific basis for precise air quality management in Shandong Province in the postpandemic period.

基于集成机器学习方法揭示2023年山东省三个时期PM2.5和O3污染反弹的驱动因素

作者:王刚1,刘赛1,王凯2,3,孟慧娟4,赵娜5,张晗宇6
机构:1中国石油大学(华东),化学与化工学院,环境与安全工程系,中国青岛,266580;2山东省生态环境规划研究院,中国济南,250101;3生态环境部陆海统筹生态治理与系统调控重点实验室,中国济南,250101;4济南工程职业技术学院,实训管理中心,中国济南,250200;5山东大学,环境研究院,中国青岛,266237;6北京工商大学,轻工科学与工程学院,环境科学与工程系,中国北京,100048
目的:2023年,随着新冠疫情防控措施调整与经济全面复苏,山东省空气质量指数出现4.3%的反弹,细颗粒物(PM2.5)和臭氧(O3)浓度均呈显著上升趋势。为揭示此次污染反弹的驱动机制,本文旨在量化人为排放与气象条件在不同季节对PM2.5和O3反弹的贡献,识别主导因素,从而为后疫情时代制定差异化的空气质量管理策略提供科学依据。
创新点:1.分时段污染驱动因素解析:针对PM2.5(早春与秋收期)和O3(光化学季)分别定义了三个关键污染期,开展分时段的驱动因素分析,以揭示不同季节主导污染物的形成机制差异;2.可解释机器学习框架构建:构建了基于树结构帕曾估计器(TPE)优化的随机森林-沙普利可加解释(RF-SHAP)集成学习框架,显著增强了模型对非线性关系的拟合能力,并实现了预测结果的可解释性。
方法:1.分时段预测模型构建:采用TPE对随机森林(RF)模型进行超参数优化,并分别针对各关键污染期(PM2.5污染期与O3光化学季)建立预测模型;将数据集按80%训练集、20%测试集划分,并评估模型性能。2.特征贡献解释:基于训练好的RF模型,运用SHAP算法计算各特征变量(以时间变量作为人为排放活动水平的代理变量,结合气象变量)对预测结果的边际贡献值。3.气象与排放贡献分离:采用"去气象"方法(重复进行1000次随机采样预测,每次随机打乱气象变量顺序以重构气象无影响情景),定量分离人为排放与气象因素对污染浓度的相对贡献。4.多维度验证:结合多尺度排放清单、卫星火点数据、典型城市(临沂)的PM2.5化学组分及挥发性有机化合物(VOC)离线采样分析结果,从排放源、火点活动、化学组成等多角度验证关键污染期的驱动机制一致性。
结论:1. PM2.5污染反弹以人为排放主导:早春期(2~4月)人为排放贡献14.1%,秋收期(9~10月)贡献19.0%;主要驱动因素为工业活动恢复(能源消费增长9.2%)与秸秆焚烧增加(火点数量上升70.0%)。2. O3污染反弹受气象影响更显著:气象条件的贡献(5.8%)高于人为排放(3.3%);关键气象因子包括大气氧化能力增强、总云量减少及边界层高度变化,但交通和石化行业的前体物排放仍是O3生成的物质基础;3.温度升高促进二次无机气溶胶生成:升温加速了SO2的液相氧化过程,并推动NH4NO3热平衡向颗粒相移动,从而强化二次无机气溶胶的形成;4.建议实施季节性差异化管控策略:春秋季应重点削减工业与农业源排放以控制PM2.5,夏季则需结合气象监测,加强对NOx和VOC等前体物的排放控制,以抑制O3生成。

关键词:空气污染反弹;驱动因素;RF-SHAP;人为排放;气象条件

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

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On-line Access: 2026-07-20

Received: 2025-12-06

Revision Accepted: 2026-04-23

Crosschecked: 2026-07-20

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 ORCID:

Hanyu ZHANG

https://orcid.org/0009-0000-7135-4197

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