Full Text:   <2773>

CLC number: O647

On-line Access: 

Received: 2004-10-25

Revision Accepted: 2005-03-01

Crosschecked: 0000-00-00

Cited: 6

Clicked: 5759

Citations:  Bibtex RefMan EndNote GB/T7714

-   Go to

Article info.
Open peer comments

Journal of Zhejiang University SCIENCE B 2005 Vol.6 No.6 P.597-601

http://doi.org/10.1631/jzus.2005.B0597


Interaction of nonionic surfactant AEO9 with ionic surfactants


Author(s):  ZHANG Zhi-guo, YIN Hong

Affiliation(s):  Department of Chemical Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding email(s):   zhiguozhang2004@yahoo.com.cn

Key Words:  Nonionic surfactant, Nonionic-ionic mixed surfactants, Molecular interaction parameter, Synergism, Mixed micelle, Mixed adsorption film


ZHANG Zhi-guo, YIN Hong. Interaction of nonionic surfactant AEO9 with ionic surfactants[J]. Journal of Zhejiang University Science B, 2005, 6(6): 597-601.

@article{title="Interaction of nonionic surfactant AEO9 with ionic surfactants",
author="ZHANG Zhi-guo, YIN Hong",
journal="Journal of Zhejiang University Science B",
volume="6",
number="6",
pages="597-601",
year="2005",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.2005.B0597"
}

%0 Journal Article
%T Interaction of nonionic surfactant AEO9 with ionic surfactants
%A ZHANG Zhi-guo
%A YIN Hong
%J Journal of Zhejiang University SCIENCE B
%V 6
%N 6
%P 597-601
%@ 1673-1581
%D 2005
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.2005.B0597

TY - JOUR
T1 - Interaction of nonionic surfactant AEO9 with ionic surfactants
A1 - ZHANG Zhi-guo
A1 - YIN Hong
J0 - Journal of Zhejiang University Science B
VL - 6
IS - 6
SP - 597
EP - 601
%@ 1673-1581
Y1 - 2005
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.2005.B0597


Abstract: 
The interaction in two mixtures of a nonionic surfactant AEO9 (C12H25O(CH2CH2O)9H) and different ionic surfactants was investigated. The two mixtures were AEO9/sodium dodecyl sulfate (SDS) and AEO9/cetyltrimethylammonium bromide (CTAB) at molar fraction of AEO9, αAEO9 The surface properties of the surfactants, critical micelle concentration (CMC), effectiveness of surface tension reduction (γCMC), maximum surface excess concentration (Γmax) and minimum area per molecule at the air/solution interface (Amin) were determined for both individual surfactants and their mixtures. The significant deviations from ideal behavior (attractive interactions) of the nonionic/ionic surfactant mixtures were determined. Mixtures of both AEO9/SDS and AEO9/CTAB exhibited synergism in surface tension reduction efficiency and mixed micelle formation, but neither exhibited synergism in surface tension reduction effectiveness.

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

Reference

[1] Bergström, M., Eriksson, J.C., 2000. A theoretical analysis of synergistic effects in mixed surfactant systems. Langmuir, 16:7173-7181.

[2] Gharibi, H., Razavizadeh, B.M., Hashemianzaheh, M., 2000. New approach for the studies of physicochemical parameters of interaction of Triton X-100 with cationic surfactants. Colloids Surf. A Physicochem. Eng. Asp., 174:375-386.

[3] Goloub, T.P., Pugh, R.J., Zhmud, B.V., 2000. Micellar interactions in nonionic/ionic mixed surfactant systems. J. Colloid Interface Sci., 229:72-81.

[4] Hou, Z.S., Li, Z.P., Wang, H.Q., 2000. The interaction of sodium dodecyl sulfonate and petroleum sulfonate with nonionic surfactants (Triton X-100, Triton X-114). Colloids Surf. A Physicochem. Eng. Asp., 166:243-249.

[5] Li, X.Z., Zhao, J.X., 2003. Effect of quaternary ammonium gemini surfactant C12-6-C12 2Br on the micellization of SDS in aqueous solution. Chin. J. Appl. Chem., 20(7):690-692 (in Chinese).

[6] Maeda, H., 1995. A simple thermodynamic analysis of the stability of ionic/nonionic mixed micelles. J. Colloid Interface Sci., 172:98-105.

[7] Matsubara, H., Muroi, S., Kameda, M., Ikeda, N., Ohta, A., Aratono, M., 2001. Interaction between ionic and nonionic surfactants in the adsorbed film and micelle. 3. sodium dodecyl sulfate and tetraethylene glycol monooctyl ether. Langmuir, 17:7752-7757.

[8] Rosen, M.J., 1989. Surfactants and Interfacial Phenomena. 2nd Ed., Wiley-Interscience, New York, p.393-419.

[9] Rosen, M.J., Zhou, Q., 2001. Surfactant-surfactant interactions in mixed monolayer and mixed micelle formation. Langmuir, 17:3532-3537.

[10] Rosen, M.J., Sulthana, S.B., 2001. The interaction of alkylglycosides with other surfactants. J. Colloid Interface Sci., 239:528-534.

[11] Shivaji Sharma, K., Rodgers, C., Palepu, R.M., Rakshit, A.K., 2003. Studies of mixed surfactant solutions of cationic dimeric (gemini) surfactant with nonionic surfactant C12E6 in aqueous medium. J. Colloid Interface Sci., 268:482-488.

[12] Zana, R., Lévy, H., Kwetkat, K., 1998. Mixed micellization of dimeric (gemini) surfactants and conventional surfactants. I. Mixtures of an anionic dimeric surfactant and of the nonionic surfactants C12E5 and C12E8. J. Colloid Interface Sci., 197:370-376.

[13] Zhao, G.X., 1991. Surfactants Physical Chemistry. Peking University Press, Beijing, p.32-47 (in Chinese).

Open peer comments: Debate/Discuss/Question/Opinion

<1>

Nisar Ahmad Malik@Jamia Millia Islami (Central University) New Delhi-India<nisarchmjmi@gmail.com>

2013-05-17 14:24:39

I found the abstract of the paper informative so please send me a soft copy of the paper to my e mail address

Dr JAOUED najeh@the doctor in INRAP in tunisia (resarch) <najehjaoued421@yahoo.fr>

2012-02-15 22:48:12

can you used the chain perfluorinated (RFO(CH2CH2)nH)and mixed with the different ionic surfactants?

and thank you

Please provide your name, email address and a comment





Journal of Zhejiang University-SCIENCE, 38 Zheda Road, Hangzhou 310027, China
Tel: +86-571-87952783; E-mail: cjzhang@zju.edu.cn
Copyright © 2000 - 2022 Journal of Zhejiang University-SCIENCE