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Journal of Zhejiang University SCIENCE A 2014 Vol.15 No.5 P.309-322

http://doi.org/10.1631/jzus.A1400063


Research and development of large-scale cryogenic air separation in China*


Author(s):  Xiao-bin Zhang1, Jian-ye Chen1, Lei Yao2, Yong-hua Huang3, Xue-jun Zhang1, Li-min Qiu1

Affiliation(s):  1. Institute of Refrigeration and Cryogenics, Zhejiang University, Hangzhou 310027, China; more

Corresponding email(s):   limin.qiu@zju.edu.cn

Key Words:  Air separation, Cryogenic, Large-scale equipment, Technological development


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Xiao-bin Zhang, Jian-ye Chen, Lei Yao, Yong-hua Huang, Xue-jun Zhang, Li-min Qiu. Research and development of large-scale cryogenic air separation in China[J]. Journal of Zhejiang University Science A, 2014, 15(5): 309-322.

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author="Xiao-bin Zhang, Jian-ye Chen, Lei Yao, Yong-hua Huang, Xue-jun Zhang, Li-min Qiu",
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volume="15",
number="5",
pages="309-322",
year="2014",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A1400063"
}

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%T Research and development of large-scale cryogenic air separation in China
%A Xiao-bin Zhang
%A Jian-ye Chen
%A Lei Yao
%A Yong-hua Huang
%A Xue-jun Zhang
%A Li-min Qiu
%J Journal of Zhejiang University SCIENCE A
%V 15
%N 5
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%D 2014
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A1400063

TY - JOUR
T1 - Research and development of large-scale cryogenic air separation in China
A1 - Xiao-bin Zhang
A1 - Jian-ye Chen
A1 - Lei Yao
A1 - Yong-hua Huang
A1 - Xue-jun Zhang
A1 - Li-min Qiu
J0 - Journal of Zhejiang University Science A
VL - 15
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SP - 309
EP - 322
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PB - Zhejiang University Press & Springer
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DOI - 10.1631/jzus.A1400063


Abstract: 
With the rapid growth in demand for industrial gas in steel and chemical industries, there has been significant emphasis placed on the development of China’s large-scale air separation technology. Currently, the maximum capacity of a single unit has been able to attain 120 000 Nm3/h (oxygen), and the specific power consumption of 0.38 kWh/m3. This paper reviews the current state-of-the-art for large-scale cryogenic air separation systems being deployed in China. A brief introduction to the history and establishment of the large-scale cryogenic air separation industry is presented. Taking the present mainstream large-scale air separation unit operating at 60 000 Nm3/h (oxygen) as an example, the technological parameters and features of the involved key equipment, including a molecular sieve adsorber, air compressor unit, plate-fin heat exchanger, turbo-expander and distillation column are described in detail. The developing 80 000–120 000 Nm3/h air separation processes and equipment are also introduced. A summary of the existing problems and future developments of these systems in China are discussed.

中国大规模空分研究进展

本文概要:中国钢铁、化工等行业对工业气体需求的快速增长,极大地促进了大规模空分技术的发展。 目前,中国生产的单套空分设备最大氧产量达到了120 000 Nm3/h,单位能耗为0.38 kWh/m3。本文介绍了中国大规模空分技术发展水平,回顾了中国大规模空分工业的发展历史。以成熟的60 000 Nm3/h空分系统为例,详细介绍了分子筛吸附器、空压机、板翅换热器、透平膨胀机和精馏塔等主要设备的技术参数。然后介绍了中国正在发展中的80 000~120 000 Nm3/h空分工艺和装备。最后讨论了中国大规模空分技术存在的主要问题及未来发展方向。
关键词:空分;深低温;大规模装置;技术发展

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

References

[1] Arp, V.D., McCarty, R.D., Friend, D.G., 1998. Thermophysical properties of helium-4 from 0.8 to 1500 K with pressures to 2000 MPa. NIST Technical Note 1334 (revised), :

[2] Bender, E., 1973. An equation of state for predicting vapor-liquid equilibrium of the system N2-Ar-O2Cryogenics, 13(1):11-18. 


[3] Chang, L., Liu, X.G., 2012. Energy optimization analysis of internal thermally coupled air separation columns. Chinese Journal of Chemical Engineering, (in Chinese),63(9):2936-2940. 

[4] Chen, G.Z., Lin, X.F., 2010. Hydrodynamic characteristics of packed columns in air separation. Chemical Engineering, (in Chinese),38(9):27-30. 

[5] Chen, H.X., Zhou, W.W., 2008. Large air separation equipment application status and development prospects. Chemical Equipment Technology, (in Chinese),29(3):12-14. 

[6] Chen, K.P., Zhong, L.N., 2009. Development status of turbo-expander technology at Hangyang. Cryogenic Technology, (in Chinese),3:58-61. 

[7] Chen, K.P., Zhong, L.N., Cai, G.C., 2010. Application of middle- and high-pressure turbine expander in large-sized air separation plant. Cryogenic Technology, (in Chinese),51:24-28. 

[8] Chi, X.L., Wu, S.M., Xiao, H.Y., 2009. Development of oxygen turbocompressor for 60000 m3/h air separation units. Cryogenic Technology, (in Chinese),3:14-17. 

[9] Gu, F.M., 2005. The present situation and prospects for the air separation trade both at home and abroad-II. Low Temperature and Specialty Gases, (in Chinese),23(5):1-5. 

[10] Gu, Y.X., 2013. Inner reports on development of experimental facilities in Hangyang Co. Ltd, (in Chinese),:

[11] Hangzhou Hangyang Co. Ltd., 2013. The main body of 120,000 air separation equipment for Iran has been finished. , Available from http://www.hangyang.com/cn/news/coMPany_news/20100218/1815411139.html,(in Chinese),:

[12] Hangzhou Hangyang Co. Ltd., 2013. Semi-annual report of 2013. , Available from http://www.hangyang.com/,(in Chinese),:

[13] Katti, R.S., Jacobsen, R.T., Stewart, R.B., 1986. Thermodynamic properties for neon for temperatures from the triple point to 700 K at pressures to 700 MPa. Advances in Cryogenic Engineering, 31:1189-1197. 


[14] Li, F.G., Ma, T.L., 2009. Analyzes of technical characteristics of air separation unit for coal-to-olefins project. Refining and Chemical Industry, (in Chinese),20:32-34. 

[15] Li, Z., 2013.  Thermodynamic Performance Potential of IGCC. (in Chinese), PhD Thesis, University of Chinese Academy of Sciences,Beijing, China :

[16] Lin, X.N., Xia, H.L., Lu, J., 2009. Development and design of a molecular sieve adsorber for 60000 m3/h air separation unit. Cryogenic Technology, (in Chinese),3:37-39. 

[17] Liu, X.M., 2013. General descriptions of development and technical innovation of global industrial gas industry. Cryogenic Technology, (in Chinese),3:26-32. 

[18] Liu, Y.J., Zhu, Y.C., 2007. The inner compressing process is optimal to large-scale air separate equipment localized at present. Application Technology, (in Chinese),:85-89. 

[19] Lu, L.W., Li, B.H., 2011. Analysis of the relationship between air separation equipment and steel industry. Science & Technology in Hangyang, (in Chinese),4:13-18. 

[20] Mao, S.R., Zhou, Z.Y., 2005. Situation and progress of large air separation unit of Hangyang. Cryogenic Technology, (in Chinese),3:3-9. 

[21] Mao, S.R., Zhu, S.Y., Zhou, Z.Y., 2005.  Technology and Operational Principal of Modern Air Separation Equipment. (in Chinese), Hangzhou Press,Hangzhou, China :

[22] Mao, S.R., Zhu, S.Y., Zhou, Z.Y., 2005.  Technology and Operation Principles of Modern Air Separation Plants. (in Chinese), Hangzhou Publishing House,Hangzhou, China :

[23] Mao, S.R., Zhu, S.Y., Zhou, Z.Y., 2012. Accelerating independent development and realizing nationalization of 80000–120000 m3/h grade large-sized air separation plant. Cryogenic Technology, (in Chinese),7:1-5. 

[24] Mao, Y.P., 1999. Typical structure of condenser-evaporator in large-scale air separation unit. Cryogenic Technology, (in Chinese),6:12-15. 

[25] Qian, B.Z., 2011. China’s first cold energy air separation plant put into use. Natural Gas and Oil, (in Chinese),29(1):41-41. 

[26] Qiu, Z.Q., Tan, H.X., Cai, S.M., 2006. The research of ASU products output balance and supply ways in metallurgy industry. China Gas, (in Chinese),:48-51. 

[27] Schmidt, R., Wagner, W., 1985. A new form of the equation of state for pure substances and its applications to oxygen. Fluid Phase Equilibria, 19(3):175-200. 


[28] Span, R., Lemmon, E.W., Jacobsen, R.T., 2000. A reference equation of state for the thermodynamic properties of nitrogen for temperatures from 63.151 to 1000 K and pressures to 2200 MPa. Journal of Physical Chemical Reference Data, 29(6):1361-1433. 


[29] Tegeler, C., Span, R., Wagner, W., 1999. A new equation of state for argon covering the fluid region for temperatures from the melting line to 700 K at pressures up to 1000 MPa. Journal of Physical and Chemical Reference Data, 28(3):779-850. 


[30] Wang, A.L., Wang, L.L., Qu, Y.G., 2007. Analysis and development on air separation technology. Science & Technology in Chemical Industry, (in Chinese),15(6):73-77. 

[31] Wang, D.W., 2009. Research and development of 4 sets of 60000 m3/h air separation units with internal compression process at Shenhua (Baotou). Cryogenic Technology, (in Chinese),3:21-24. 

[32] Wang, J.H., 2009. Development of plate-fin heat exchanger at Hangyang. General Machinery, (in Chinese),12:22-25. 

[33] Wu, Q.X., 1998. Introduction of New Technologies of ASU of Companies in Germany, USA and France. Cryogenic Technology, (in Chinese),5:5-8. 

[34]  , 2013. China’s synthetic ammonia production data statistics in 2012. , Available from http://www.askci.com/news/201303/20/2017494481765.html,(in Chinese),:

[35]  , 2013. China’s ethylene production data statistics in 2012. , Available from http://www.askci.com/news/201303/20/201731881759.shtml,(in Chinese),:

[36]  , 2013. Global steel production in 2012. , Available from http://www.guancha.cn/Industry/2013_01_25_123060.html,(in Chinese),:

[37]  , 2012. The first large air compressor unit break the foreign monopoly. http://info.hvacr.hc360.com/2012/10/180930462867.shtml,(in Chinese),:

[38]  , 2012. AP Co. will supply gas for a new electronics memory chip factory of Samsung in Xi’an. , Available from http://sx.sina.com.cn/news/zhichi/2012-07-18/37989.html,(in Chinese),:

[39]  , 2013. The test run of China’s first set of air separation multi-axis pressurization units is successful by Shanngu Co. , Available from http://www.sxdaily.com.cn/n/2013/0226/c266-5081199.html,(in Chinese),:

[40] Xia, H.L., Lin, X.N., Li, J.F., 2013. Research and application of large-sized radial flow molecular sieve adsorber. Cryogenic Technology, (in Chinese),2:18-22. 

[41] Yang, X.L., Ma, J.C., 2010. Development of rectification tower of large-sized air separation plant. Cryogenic Technology, (in Chinese),51:1-3. 

[42] Yang, Y.Y., Deng, W., 2005. Joint development of steel and gas. , Fifteenth Gas Industry Development Seminar, Hangzhou, :

[43] Yang, Y.Y., Deng, W., 2012. Further discuss on joint development of steel and gas. , Available from http://www.kongfen.cc,(in Chinese),:

[44] Yao, L., Qiu, L.M., Zhou, Z.Y., 2010. Cryogenic air separation industry in China: past, present and future. , Proceedings of International Cryogenic Engineering Conference-23, Poland, :

[45] Ye, C.Q., 2012. Technological reports on the compressor unit for large-scale air separation, (in Chinese), Xian Shaangu Power Co. Ltd,:

[46] Yu, Q., Huang, Y., 2013. Research on critical thermodynamic properties of air-product fluids. Chinese Journal of Low Temperature Physics, (in Chinese),35(1):61-68. 

[47] Zhang, X.B., Yao, L., Qiu, L.M., 2013. Three-dimensional computational fluid dynamics modeling of two-phase flow in a structured packing column. Chinese Journal of Chemical Engineering, 21(9):959-966. 


[48] Zhou, Z.Y., Han, Y.S., 2009. Development status of modern coal-chemical industry type air separation unit. Cryogenic Technology, (in Chinese),3:47-51. 


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