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Journal of Zhejiang University SCIENCE A 2004 Vol.5 No.5 P.603-608


Study of transport behavior for Fe-doping La0.67Ca0.33MnO3 perovskite manganese

Author(s):  CUI Yu-jian, GE Hong-liang, HAN Yan-bing, JIA Guang-qiang, WANG Xin-yan, CAO Yi-gang, ZHANG Jin-cang

Affiliation(s):  Department of Physics, China Institute of Metrology, Hangzhou 310018, China; more

Corresponding email(s):   yjcui@cim.edu.cn

Key Words:  La2/3Ca1/3MnO3, Fe-doping, Crystal structure, Transport properties

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CUI Yu-jian, GE Hong-liang, HAN Yan-bing, JIA Guang-qiang, WANG Xin-yan, CAO Yi-gang, ZHANG Jin-cang. Study of transport behavior for Fe-doping La0.67Ca0.33MnO3 perovskite manganese[J]. Journal of Zhejiang University Science A, 2004, 5(5): 603-608.

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journal="Journal of Zhejiang University Science A",
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A1 - CUI Yu-jian
A1 - GE Hong-liang
A1 - HAN Yan-bing
A1 - JIA Guang-qiang
A1 - WANG Xin-yan
A1 - CAO Yi-gang
A1 - ZHANG Jin-cang
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Systematic studies of the transport properties of La0.67Ca0.33Mn1-xFexO3 (x=0-0.3) systems showed that with increasing fe-doping content x the resistance increases and the insulator-metal transition temperature moves to lower temperature. For small doping content, the transport property satisfies metal transport behavior below the transition temperature, and above the transition temperature it satisfies the small polaron model. This behavior can be explained by Fe3+ doping, which easily forms Fe3+-O2--Mn4+ channel, suppressing the double exchange Mn3+-O2--Mn4+ channel and enhancing the spin scattering of Mn ions induced by antiferromagnetic clusters of Fe ions.

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article


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