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CLC number: TQ31; O63

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Received: 2008-05-03

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Journal of Zhejiang University SCIENCE A 2008 Vol.9 No.9 P.1304-1308

http://doi.org/10.1631/jzus.A0820162


Synthesis of poly[methyl(3,3,3-trifluoropropyl)siloxane]-b-poly(ethylene oxide) block copolymers


Author(s):  Xiao-li ZHAN, Bi CHEN, Qing-hua ZHANG, Ling-min YI, Bo JIANG, Feng-qiu CHEN

Affiliation(s):  College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China; more

Corresponding email(s):   qhzhang@zju.edu.cn

Key Words:  Block copolymers, Polysiloxanes, Fluoropolymers, Synthesis, Polyethyleneoxide


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Xiao-li ZHAN, Bi CHEN, Qing-hua ZHANG, Ling-min YI, Bo JIANG, Feng-qiu CHEN. Synthesis of poly[methyl(3,3,3-trifluoropropyl)siloxane]-b-poly(ethylene oxide) block copolymers[J]. Journal of Zhejiang University Science A, 2008, 9(9): 1304-1308.

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author="Xiao-li ZHAN, Bi CHEN, Qing-hua ZHANG, Ling-min YI, Bo JIANG, Feng-qiu CHEN",
journal="Journal of Zhejiang University Science A",
volume="9",
number="9",
pages="1304-1308",
year="2008",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A0820162"
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%T Synthesis of poly[methyl(3,3,3-trifluoropropyl)siloxane]-b-poly(ethylene oxide) block copolymers
%A Xiao-li ZHAN
%A Bi CHEN
%A Qing-hua ZHANG
%A Ling-min YI
%A Bo JIANG
%A Feng-qiu CHEN
%J Journal of Zhejiang University SCIENCE A
%V 9
%N 9
%P 1304-1308
%@ 1673-565X
%D 2008
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A0820162

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T1 - Synthesis of poly[methyl(3,3,3-trifluoropropyl)siloxane]-b-poly(ethylene oxide) block copolymers
A1 - Xiao-li ZHAN
A1 - Bi CHEN
A1 - Qing-hua ZHANG
A1 - Ling-min YI
A1 - Bo JIANG
A1 - Feng-qiu CHEN
J0 - Journal of Zhejiang University Science A
VL - 9
IS - 9
SP - 1304
EP - 1308
%@ 1673-565X
Y1 - 2008
PB - Zhejiang University Press & Springer
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DOI - 10.1631/jzus.A0820162


Abstract: 
A series of new amphiphilic poly[methyl(3,3,3-trifluoropropyl)siloxane]-b-poly(ethylene oxide) (PMTFPS-b-PEO) diblock copolymers with different ratios of hydrophobic segment to hydrophilic segment were prepared by coupling reactions of end-functional PMTFPS and PEO homopolymers. Copolymers were shown to be well defined and narrow molecular weight distribution (MWD) (1.07~1.3) by characterizations such as gel permeation chromatography (GPC) and 1H-nudear magnetic resonance (1H-NMR).

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

Reference

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