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CLC number: TQ31; O63

On-line Access: 2024-08-27

Received: 2023-10-17

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Journal of Zhejiang University SCIENCE A 2008 Vol.9 No.9 P.1304-1308

http://doi.org/10.1631/jzus.A0820162


Synthesis of poly[methyl(3,3,3-trifluoropropyl)siloxane]-b-poly(ethylene oxide) block copolymers


Author(s):  Xiao-li ZHAN, Bi CHEN, Qing-hua ZHANG, Ling-min YI, Bo JIANG, Feng-qiu CHEN

Affiliation(s):  College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China; more

Corresponding email(s):   qhzhang@zju.edu.cn

Key Words:  Block copolymers, Polysiloxanes, Fluoropolymers, Synthesis, Polyethyleneoxide


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Xiao-li ZHAN, Bi CHEN, Qing-hua ZHANG, Ling-min YI, Bo JIANG, Feng-qiu CHEN. Synthesis of poly[methyl(3,3,3-trifluoropropyl)siloxane]-b-poly(ethylene oxide) block copolymers[J]. Journal of Zhejiang University Science A, 2008, 9(9): 1304-1308.

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author="Xiao-li ZHAN, Bi CHEN, Qing-hua ZHANG, Ling-min YI, Bo JIANG, Feng-qiu CHEN",
journal="Journal of Zhejiang University Science A",
volume="9",
number="9",
pages="1304-1308",
year="2008",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A0820162"
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%T Synthesis of poly[methyl(3,3,3-trifluoropropyl)siloxane]-b-poly(ethylene oxide) block copolymers
%A Xiao-li ZHAN
%A Bi CHEN
%A Qing-hua ZHANG
%A Ling-min YI
%A Bo JIANG
%A Feng-qiu CHEN
%J Journal of Zhejiang University SCIENCE A
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%@ 1673-565X
%D 2008
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A0820162

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T1 - Synthesis of poly[methyl(3,3,3-trifluoropropyl)siloxane]-b-poly(ethylene oxide) block copolymers
A1 - Xiao-li ZHAN
A1 - Bi CHEN
A1 - Qing-hua ZHANG
A1 - Ling-min YI
A1 - Bo JIANG
A1 - Feng-qiu CHEN
J0 - Journal of Zhejiang University Science A
VL - 9
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SP - 1304
EP - 1308
%@ 1673-565X
Y1 - 2008
PB - Zhejiang University Press & Springer
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DOI - 10.1631/jzus.A0820162


Abstract: 
A series of new amphiphilic poly[methyl(3,3,3-trifluoropropyl)siloxane]-b-poly(ethylene oxide) (PMTFPS-b-PEO) diblock copolymers with different ratios of hydrophobic segment to hydrophilic segment were prepared by coupling reactions of end-functional PMTFPS and PEO homopolymers. Copolymers were shown to be well defined and narrow molecular weight distribution (MWD) (1.07~1.3) by characterizations such as gel permeation chromatography (GPC) and 1H-nudear magnetic resonance (1H-NMR).

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

Reference

[1] Elkins, C.L., Long, T.E., 2004. Living anionic polymerization of hexamethylcyclotrisiloxane (D3) using functionalized initiation. Macromolecules, 37(17):6657-6659.

[2] Gilman, H., Cartledge, F., 1964. The analysis of organolithium compounds. Journal of Organometallic Chemistry, 2(6):447-454.

[3] Grubisic, Z., Rempp, P., Benoit, H., 1996. A universal calibration for gel permeation chromatography. Journal of Polymer Science Part B: Polymer Physics, 34(10):1707-1713.

[4] Kickelbick, G., Bauer, J., Huesing, N., Andersson, M., Palmqvist, A., 2003a. Spontaneous vesicle formation of short-chain amphiphilic polysiloxane-b-poly(ethylene oxide) block copolymers. Langmuir, 19(8):3198-3210.

[5] Kickelbick, G., Bauer, J., Huesing, N., Andersson, M., Holmberg, K.A., 2003b. Aggregation behavior of short-chain PDMS-b-PEO diblock copolymers in aqueous solutions. Langmuir, 19(24):10073-10076.

[6] Lin, Z., Hill, R.M., Davis, H.T., Scriven, L.E., Talmon, Y., 1994. Cryo transmission electron microscopy study of vesicles and micelles in siloxane surfactant aqueous solutions. Langmuir, 10(4):1008-1011.

[7] Robert, E., Fighter, J., Godin, N., Boscher, Y., 1997. Discussion on round-robin testing in size exclusion chromatography using polyamides as an example. International Journal of Polymer Analysis and Characterization, 3(4):351-358.

[8] Rosen, M.J., Wu, Y., 2001. Superspreading of trisiloxane surfactant mixtures on hydrophobic surfaces. 1. Interfacial adsorption of aqueous trisiloxane surfactant-N-alkyl pyrrolidinone mixtures on polyethylene. Langmuir, 17(23):7296-7305.

[9] Wu, Y., Rosen, M.J., 2002. Superspreading of trisiloxane surfactant mixtures on hydrophobic surfaces. 2. Interaction and spreading of aqueous trisiloxane surfactant-N-alkyl-pyrrolidinone mixtures in contact with polyethylene. Langmuir, 18(6):2205-2215.

[10] Yi, L., Zhan, X., Chen, F., Du, F., Huang, L., 2005. Synthesis and characterization of poly[styrene-b-methyl(3,3,3-trifluoropropyl)siloxane] diblock copolymers via anionic polymerization. Journal of Polymer Science Part A: Polymer Chemistry, 43(19):4431-4438.

[11] Zhang, Q.H., Zhan, X.L., Chen, F.Q., Shi, Y., Wang, Q.Y., 2007. Block copolymers of dodecafluoroheptyl methacrylate and Butyl methacrylate by RAFT miniemulsion polymerization. Journal of Polymer Science Part A: Polymer Chemistry, 45(9):1585-1594.

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