CLC number: O646
On-line Access: 2024-08-27
Received: 2023-10-17
Revision Accepted: 2024-05-08
Crosschecked: 2016-01-25
Cited: 0
Clicked: 5384
Xin-yue Zhao, Jing-lun Wang, Hao Luo, Hu-rong Yao, Chu-ying Ouyang, Ling-zhi Zhang. A novel organosilicon-based ionic plastic crystal as solid-state electrolyte for lithium-ion batteries[J]. Journal of Zhejiang University Science A, 2016, 17(2): 155-162.
@article{title="A novel organosilicon-based ionic plastic crystal as solid-state electrolyte for lithium-ion batteries",
author="Xin-yue Zhao, Jing-lun Wang, Hao Luo, Hu-rong Yao, Chu-ying Ouyang, Ling-zhi Zhang",
journal="Journal of Zhejiang University Science A",
volume="17",
number="2",
pages="155-162",
year="2016",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A1500099"
}
%0 Journal Article
%T A novel organosilicon-based ionic plastic crystal as solid-state electrolyte for lithium-ion batteries
%A Xin-yue Zhao
%A Jing-lun Wang
%A Hao Luo
%A Hu-rong Yao
%A Chu-ying Ouyang
%A Ling-zhi Zhang
%J Journal of Zhejiang University SCIENCE A
%V 17
%N 2
%P 155-162
%@ 1673-565X
%D 2016
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A1500099
TY - JOUR
T1 - A novel organosilicon-based ionic plastic crystal as solid-state electrolyte for lithium-ion batteries
A1 - Xin-yue Zhao
A1 - Jing-lun Wang
A1 - Hao Luo
A1 - Hu-rong Yao
A1 - Chu-ying Ouyang
A1 - Ling-zhi Zhang
J0 - Journal of Zhejiang University Science A
VL - 17
IS - 2
SP - 155
EP - 162
%@ 1673-565X
Y1 - 2016
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.A1500099
Abstract: A novel organosilicon-based ionic plastic crystal, N,N,N,-diethylmethyl-N-[(trimethylsilyl)methyl]ammonium bistrifluoromethane sulfonimide ([DTMA][TFSI]) was designed and synthesized as solid-state electrolyte for lithium-ion batteries. The chemical structure and the physical and electrochemical properties were characterized in detail. The ionic conductivity of [DTMA][TFSI] was improved significantly by doping with lithium oxalyldifluoroborate (LiODFB) and propylene carbonate (PC). An optimized plastic crystal composite ([DTMA][TFSI]:LiODFB:PC=8:1: molar ratio) as a solid-state electrolyte exhibited a decent cycling stability in LiFePO4/Li half-cell, with a specific discharge capacity of 144 mA·h/g and capacity retention of 94% after 50 cycles at C/20.
This is a solid paper describing relevant and interesting work on the use of organic plastic crystals in Li-Bat applications.
[1]Abu-Lebdeh, Y., Abouimrane, A., Alarco, P.J., et al., 2004. Ambient temperature proton conducting plastic crystal electrolytes. Electrochemistry Communications, 6(4):432-434.
[2]Alarco, P.J., Abu-Lebdeh, Y., Ravet, N., et al., 2004. Lithium conducting pyrazolium imides plastic crystals: a new solid state electrolyte matrix. Solid State Ionics, 172(1-4):53-56.
[3]Armel, V., Velayutham, D., Sun, J.Z., et al., 2011. Ionic liquids and organic ionic plastic crystals utilizing small phosphonium cations. Journal of Materials Chemistry, 21(21):7640-7650.
[4]Forsyth, M., Huang, J., MacFarlane, D.R., 2000. Lithium doped N-methyl-N-ethylpyrrolidinium bis(trifluorome-thanesulfonyl)amide fast-ion conducting plastic crystals. Journal of Materials Chemistry, 10(10):2259-2265.
[5]Glasse, M.D., Idris, R., Latham, R.J., et al., 2002. Polymer electrolytes based on modified natural rubber. Solid State Ionics, 147(3-4):289-294.
[6]Hammami, A., Raymond, N., Armand, M., 2003. Runaway risk of forming toxic compounds. Nature, 424(6949):635-636.
[7]Hasegawa, E., Brumfield, M.A., Mariano, P.S., et al., 1988. Photoadditions of ethers, thioethers, and amines to 9, 10-dicyanoanthracene by electron-transfer pathways. Journal of Organic Chemistry, 53(23):5435-5442.
[8]Horike, S., Umeyama, D., Inukai, M., et al., 2012. Coordination-network-based ionic plastic crystal for anhydrous proton conductivity. Journal of the American Chemical Society, 134(18):7612-7615.
[9]Howlett, P.C., Sunarso, J., Shekibi, Y., et al., 2011. On the use of organic ionic plastic crystals in all solid-state lithium metal batteries. Solid State Ionics, 204-205:73-79.
[10]Kim, H., Nguyen, D.Q., Bae, H.W., et al., 2008. Effect of ether group on the electrochemical stability of zwitterionic imidazolium compounds. Electrochemistry Communications, 10(11):1761-1764.
[11]MacFarlane, D.R., Forsyth, M., 2001. Plastic crystal electrolyte materials: new perspectives on solid state ionics. Advanced Materials, 13(12-13):957-966.
[12]MacFarlane, D.R., Meakin, P., Amini, N., et al., 2001. Structural studies of ambient temperature plastic crystal ion conductors. Journal of Physics: Condensed Matter, 13(36):8257-8267.
[13]Moriya, M., Watanabe, T., Nabeno, S., et al., 2014. Crystal structure and solid-state ionic conductivity of cyclic sulfonylamide salts with cyano-substituted quaternary ammonium cations. Chemistry Letters, 43(1):108-110.
[14]Osman, Z., Ibrahim, Z.A., Arof, A.K., 2001. Conductivity enhancement due to ion dissociation in plasticized chitosan based polymer electrolytes. Carbohydrate Polymers, 44(2):167-173.
[15]Pringle, J.M., 2013. Recent progress in the development and use of organic ionic plastic crystal electrolytes. Physical Chemistry Chemical Physics, 15(5):1339-1351.
[16]Qin, X.Y., Wang, J.L., Tang, D.P., et al., 2013. Triethoxysilane with oligo(ethylene oxide) substituent as film forming additive for graphite anode. Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 14(7):514-519.
[17]Rana, U.A., Forsyth, M., MacFarlane, D.R., et al., 2012. Toward protic ionic liquid and organic ionic plastic crystal electrolytes for fuel cells. Electrochimica Acta, 84:213-222.
[18]Rossi, N.A.A., West, R., 2009. Silicon-containing liquid polymer electrolytes for application in lithium ion batteries. Polymer International, 58(3):267-272.
[19]Ruther, T., Huang, J., Hollenkamp, A.F., 2007. A new family of ionic liquids based on N,N-dialkyl-3-azabicyclo [3.2.2]nonanium cations: organic plastic crystal behaviour and highly reversible lithium metal electrodeposition. Chemical Communications, 48:5226-5228.
[20]Shekibi, Y., Ruther, T., Huang, J.H., et al., 2012. Realisation of an all solid state lithium battery using solid high temperature plastic crystal electrolytes exhibiting liquid like conductivity. Physical Chemistry Chemical Physics, 14(13):4597-4604.
[21]Shirota, H., Castner, E.W., 2005. Why are viscosities lower for ionic liquids with –CH2Si(CH3)3 vs –CH(CH3)3 substitutions on the imidazolium cations Journal of Physical Chemistry B, 109(46):21576-21585.
[22]Sunarso, J., Shekibi, Y., Efthimiadis, J., et al., 2012. Optimising organic ionic plastic crystal electrolyte for all solid-state and higher than ambient temperature lithium batteries. Journal of Solid State Electrochemistry, 16(5):1841-1848.
[23]Taniki, R., Matsumoto, K., Nohira, T., et al., 2014. All solid-state electrochemical capacitors using N,N-dimethylpyrrolidinium fluorohydrogenate as ionic plastic crystal electrolyte. Journal of Power Sources, 245:758-763.
[24]Tarascon, J.M., Armand, M., 2001. Issues and challenges facing rechargeable lithium batteries. Nature, 414(6861):359-367.
[25]Timmermans, J., 1961. Plastic crystals—a historical review. Journal of Physics and Chemistry of Solids, 18(1):1-8.
[26]Unemoto, A., Gambe, Y., Komatsu, D., et al., 2014. Development of high capacity all-solid-state lithium battery using quasi-solid-state electrolyte containing tetraglyme –Li-TFSA equimolar complexes. Solid State Ionics, 262:765-768.
[27]Wang, Y.F., Zhang, J.M., Cui, X.R., et al., 2013. A novel organic ionic plastic crystal electrolyte for solid-state dye-sensitized solar cells. Electrochimica Acta, 112:247-251.
[28]Weng, W., Zhang, Z.C., Lu, J., et al., 2011. A disiloxane-functionalized phosphonium-based ionic liquid as electrolyte for lithium-ion batteries. Chemical Communications, 47(43):11969-11971.
[29]Yan, X.D., Zhang, L.Z., 2013. Polyethylene glycol-modified poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) counter electrodes for dye-sensitized solar cell. Journal of Applied Electrochemistry, 43(6):605-610.
[30]Yong, T.Q., Wang, J.L., Mai, Y.J., et al., 2014. Organosilicon compounds containing nitrile and oligo(ethylene oxide) substituents as safe electrolytes for high-voltage lithium-ion batteries. Journal of Power Sources, 254:29-32.
[31]Zhang, H.P., Fu, L.J., Wu, Y.P., et al., 2007. Changes of LiCoO2 cathode material for lithium-ion battery during long cycling. Electrochemical and Solid-State Letters, 10(12):A283-A285.
[32]Zhang, L.Z., Zhang, Z.C., Harring, S., et al., 2008. Highly conductive trimethylsilyl oligo(ethylene oxide) electrolytes for energy storage applications. Journal of Materials Chemistry, 18(31):3713-3717.
[33]Zhang, S.S., 2006. An unique lithium salt for the improved electrolyte of Li-ion battery. Electrochemistry Communications, 8(9):1423-1428.
[34]Zhong, H.X., Zhao, C.B., Luo, H., et al., 2012. Novel organosilicon ionic liquid based electrolytes for supercapacitors. Acta Physico-Chimica Sinica, 28(11):2641-2647.
Open peer comments: Debate/Discuss/Question/Opinion
<1>