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CLC number: O621.14+4
On-line Access: 2024-08-27
Received: 2023-10-17
Revision Accepted: 2024-05-08
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A SIMPLE METHOD FOR CHIRAL RESOLUTION OF 1,1'-BI-2-NAPHTHOL
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LI Xiao-tao, JIANG Guang-guang, CHEN Wei-xiang, XU Zhu-de. A SIMPLE METHOD FOR CHIRAL RESOLUTION OF 1,1'-BI-2-NAPHTHOL[J]. Journal of Zhejiang University Science A, 2001, 2(3): 275-277.
@article{title="A SIMPLE METHOD FOR CHIRAL RESOLUTION OF 1,1'-BI-2-NAPHTHOL",
author="LI Xiao-tao, JIANG Guang-guang, CHEN Wei-xiang, XU Zhu-de",
journal="Journal of Zhejiang University Science A",
volume="2",
number="3",
pages="275-277",
year="2001",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.2001.0275"
}
%0 Journal Article
%T A SIMPLE METHOD FOR CHIRAL RESOLUTION OF 1,1'-BI-2-NAPHTHOL
%A LI Xiao-tao
%A JIANG Guang-guang
%A CHEN Wei-xiang
%A XU Zhu-de
%J Journal of Zhejiang University SCIENCE A
%V 2
%N 3
%P 275-277
%@ 1869-1951
%D 2001
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.2001.0275
TY - JOUR
T1 - A SIMPLE METHOD FOR CHIRAL RESOLUTION OF 1,1'-BI-2-NAPHTHOL
A1 - LI Xiao-tao
A1 - JIANG Guang-guang
A1 - CHEN Wei-xiang
A1 - XU Zhu-de
J0 - Journal of Zhejiang University Science A
VL - 2
IS - 3
SP - 275
EP - 277
%@ 1869-1951
Y1 - 2001
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.2001.0275
Abstract: An improved method for preparing enantiomerically pure 1,1'-bi-2-naphthols is described. 1,1'-bi-2-naphthol boric anhydride was generated from the reaction of racemic 1,1'-bi-2-naphthol and boric anhydride. Its two diastereoisomers could be efficiently separated in THF using (L)-proline as the resolving agent. Treatment in three successive steps yielded 79% and 74% enantiomerically pure (S)- and (R)-1,1'-bi-2-naphthol respectively.
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