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Received: 2004-09-16

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Journal of Zhejiang University SCIENCE B 2005 Vol.6 No.5 P.365-368


Influence of surfactant concentration on counter-ion induced solubility of poly(pyridine-2,5-diyl)

Author(s):  IMIT Mokhtar, YAMAMOTO Takakazu, IMIN Patigul

Affiliation(s):  School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China; more

Corresponding email(s):   mokhtarjan@sohu.com

Key Words:  Poly(pyridine-2, 5-diyl), Counter-ion solubility, Surfactants

IMIT Mokhtar, YAMAMOTO Takakazu, IMIN Patigul. Influence of surfactant concentration on counter-ion induced solubility of poly(pyridine-2,5-diyl)[J]. Journal of Zhejiang University Science B, 2005, 6(5): 365-368.

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author="IMIT Mokhtar, YAMAMOTO Takakazu, IMIN Patigul",
journal="Journal of Zhejiang University Science B",
publisher="Zhejiang University Press & Springer",

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%T Influence of surfactant concentration on counter-ion induced solubility of poly(pyridine-2,5-diyl)
%A IMIT Mokhtar
%A YAMAMOTO Takakazu
%A IMIN Patigul
%J Journal of Zhejiang University SCIENCE B
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%@ 1673-1581
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%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.2005.B0365

T1 - Influence of surfactant concentration on counter-ion induced solubility of poly(pyridine-2,5-diyl)
A1 - IMIT Mokhtar
A1 - YAMAMOTO Takakazu
A1 - IMIN Patigul
J0 - Journal of Zhejiang University Science B
VL - 6
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SP - 365
EP - 368
%@ 1673-1581
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PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.2005.B0365

Protonating the pyridine rings of poly(pyridine-2,5-diyl) with dodecybenzenesulfonic acid and camphorsulphonic acid produces polymer materials which can be dissolved in chloroform (in contrast to the unprotonated polymer, which can only be dissolved in strong acids such as formic acid) and allows mixing the protonated polymers with other chloroform soluble conjugated polymers for use in electronic devices. The protonating behavior of poly(pyridine-2,5-diyl) with two kinds of surfactants is different in some levels. Dodecybenzenesulfonic acid has higher protonating ability than camphorsulphonic acid.

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article


[1] Ikkala, O., ten Brinke, G., 2002. Functional materials based on self-assembly of polymeric supramolecules. Science, 295:2407-2409.

[2] Jonforsen, M., Grigalevicius, S., Andersson, M.R., Hjertberg, T., 1999. Counter-ion induced solubility of polypyridines. Synth. Met., 102:1200-1201.

[3] Knaapila, M., Ruokolainen, J., Ikkala, O., Torkkeli, M., Serimaa, R., Horsburgh, L., Monkman, A.P., Bras, W., ten Brinke, G., 2001. Self-organized supramolecules of poly (2,5-pyridinediyl). Synth. Met., 121:1257-1257.

[4] Monkman, A.P., Halim, M., Samuel, I.D.W., Horsberg, L.E., 1998. Protonation effects on the photophysical properties of poly(2,5-pyridinediyl). J. Chem. Phys., 109:10372-10378.

[5] Nalwa, H.S., 1997. Handbook of Organic Conductive Molecules and Polymers. John Wiley, Chichester.

[6] Nurulla, I., Morikita, T., Fukumoto, H., Yamamoto, T., 2001. Preparation and properties of poly[(2-alkylbenzimidazole)-alt-thiophene]s with long alkyl side chains. Macromol. Chem. Phys., 202:2335-2340.

[7] Skotheim, T.A., Elsenbaumer, R.L., Reynolds, J.R., 1997. Handbook of Conducting Polymers. Marcel Dekker, New York.

[8] Yamamoto, T., 2002. π-conjugated polymers with electronic and optical functionalities: preparation by organometallic polyconden-sation, properties and applications. Maromol. Rapid Commun., 23:583-606.

[9] Yamamoto, T., Ito, T., Kubota, K.A., 1988. Soluble poly(arylene) with large degree of depolar-zation of anisotropy. poly(2,5-pyridinediyl) prepared by dehalogenation polycondensation of 2,5-dibromopyridine with Ni(0)-complexes. Chem. Lett., 17:153-154.

[10] Yamamoto, T., Maruyama, T., Zhou, Z.H., Ito, T., Fukuda, T., Yoneda, Y., Begum, F., Ikeda, T., 1994. P-conjugated poly(pyridine-2,5-diyl), poly(2,2'-bipyridine-5,5'-diyl), and their alkyl derivatives, preparation, linear structure, function as ligand to form their transition metal complexes, catalytic reactions, n-type electrically conducting properties, optical properties and alignment on substrates. J. Am. Chem. Soc., 116:4832-4840.

[11] Yamamoto, T., Nakamura, T., Fukumoto, H., 2001. Preparation and characterization of regioregular head-to-tail π-conjugated poly(pyridine-2,5-diyl)s. Chem. Lett., 30:502-504.

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