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Journal of Zhejiang University SCIENCE A 2009 Vol.10 No.5 P.710-715

http://doi.org/10.1631/jzus.A0820736


Partially reversible photochromic behavior of organic-inorganic perovskites with copper(II) chloride


Author(s):  Xiao-wei PAN, Gang WU, Mang WANG, Hong-zheng CHEN

Affiliation(s):  State Key Lab of Silicon Materials, MOE Key Laboratory of Macromolecule Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding email(s):   wmang@zju.edu.cn

Key Words:  Photochromic behavior, Perovskite, Organic-inorganic hybrid


Xiao-wei PAN, Gang WU, Mang WANG, Hong-zheng CHEN. Partially reversible photochromic behavior of organic-inorganic perovskites with copper(II) chloride[J]. Journal of Zhejiang University Science A, 2009, 10(5): 710-715.

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author="Xiao-wei PAN, Gang WU, Mang WANG, Hong-zheng CHEN",
journal="Journal of Zhejiang University Science A",
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publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A0820736"
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%T Partially reversible photochromic behavior of organic-inorganic perovskites with copper(II) chloride
%A Xiao-wei PAN
%A Gang WU
%A Mang WANG
%A Hong-zheng CHEN
%J Journal of Zhejiang University SCIENCE A
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%@ 1673-565X
%D 2009
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A0820736

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T1 - Partially reversible photochromic behavior of organic-inorganic perovskites with copper(II) chloride
A1 - Xiao-wei PAN
A1 - Gang WU
A1 - Mang WANG
A1 - Hong-zheng CHEN
J0 - Journal of Zhejiang University Science A
VL - 10
IS - 5
SP - 710
EP - 715
%@ 1673-565X
Y1 - 2009
PB - Zhejiang University Press & Springer
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DOI - 10.1631/jzus.A0820736


Abstract: 
We report that the ultraviolet (UV) light induced photochromic behavior of layered organic-inorganic perovskite material of (C4H9NH3)2CuCl4, changed from yellow to brown after irradiation with UV light (10 mW/cm2) and partially recovered through storage in the dark. (C4H9NH3)2CuCl4 exhibited two distinct absorption bands centered at 286 nm (band I) and 384 nm (band II), which were attributed to the photo-induced exciton formed in 2D inorganic layers sandwiched by organic layers. The blue shift of band I from 287 to 269 nm as well as the decrease of the intensity of band I and band II could be found when samples were irradiated under UV light for different length of time. The simultaneous weakening of the intensity of the N−H···Cl hydrogen bond as well as the vibration of the long Cu−Cl bond in the distorted CuCl64− octahedron could be detected from the Fourier transform infrared (FTIR) spectra, which resulted the change of charge distribution of the dissymmetric Cl−Cu···Cl bond and the resulting photochromic behavior.

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Reference

[1] Cheng, Z.Y., Wang, Z., Xing, R.B., Han, Y.C., Lin, J., 2003. Patterning and photoluminescent properties of perovskite-type organic/inorganic hybrid luminescent films by soft lithography. Chemical Physics Letters, 376(3-4):481-486.

[2] Geraud, E., Möhwald, H., Shchukin, D.G., 2008. Templating of perovskite-related films using layer-by-layer assemblies and nanoparticle building blocks. Chemistry of Materials, 20(16):5139-5145.

[3] Jain, P., Dalal, N.S., Toby, B.H., Kroto, H.W., Cheetham, A.K., 2008. Order-disorder antiferroelectric phase transition in a hybrid inorganic-organic framework with the perovskite architecture. Journal of the American Chemical Society, 130(32):10450-10451.

[4] Li, Y., Zheng, G., Lin, C., Lin, J., 2008. New organic-inorganic perovskite materials with different optical properties modulated by different inorganic sheets. Crystal Growth & Design, 8(6):1990-1996.

[5] Mitzi, D.B., 1996. Synthesis, crystal structure, and optical and thermal properties of (C4H9NH3)2MI4 (M=Ge, Sn, Pb). Chemistry of Materials 8:791-800.

[6] Mitzi, D.B., 2001. Thin-film deposition of organic-inorganic hybrid materials. Chemistry of Materials, 13(10):3283-3298.

[7] Mitzi, D.B., 2004. Solution-processed inorganic semiconductors. Journal of Materials Chemistry, 14(15):2355-2365.

[8] Myles, A.J., Wigglesworth, T.J., Branda, N.R., 2003. A multi-addressable photochromic 1,2-dithienylcyclo-pentene-phenoxynaphthacenequinone hybrid. Advanced Materials, 15(9):745-748.

[9] Rodriguez, F., Aguado, F., Valiente, R., Hanfland, M., Itie, J.P., 2007. Variation of the Jahn-Teller distortion with pressure in perovskite layers A2CuCl4. Influence on the charge-transfer band. Physica Status Solidi (B), 24:156-161.

[10] Sourisseau, S., Louvain, N., Bi, W.H., Mercier, N., Rondeau, D., Buzaré, J.Y., Legein, C., 2007. Hybrid perovskite resulting from the solid-state reaction between the organic cations and perovskite layers of α1-(Br-(CH2)2-NH3)2PbI4. Inorganic Chemistry, 46:6148-6154.

[11] Smith, D.W., 1976. Chlorocuprates(II). Coordination Chemistry Reviews, 21(2-3):93-260.

[12] Valiente, R., Rodriguez, F., 1996. Polarized electronic spectra of the (CH3NH3)2Cd1−xMnxCl4 (x=0~1) perovskite layer doped with Cu2+: Study of the Cl→Cu2+ charge transfer intensity enhancement along the series. Journal of Physics and Chemistry of Solids, 57:571-578.

[13] Valiente, R., Rodriguez, F., 1999. Electron-phonon coupling in charge-transfer and crystal-field states of Jahn-Teller CuCl64 systems. Physical Review B, 60(13):9423-9429.

[14] Valiente, R., Rodriguez, F., Moreno, M., Hitchman, M., 1999. Effect of pressure on the Cl→Cu2+ charge transfer in A2CuCl4 layer perovskites (A=CnH2n+1NH3, n=2, 3) and (3-Chloroanilinium)8[CuCl6]Cl4: structural correlations. Physica B: Condensed Matter, 265(1-4):176-180.

[15] Wselucha-Birczynska, A., Pluszkiewicz, C., Borzecka-Prolop, B., 2003. FTIR and XRD studies of the temperature changes in copper(II)-cinchoninium compound: the importance of the sample preparation. Journal of Molecular Structure, 651:525-531.

[16] Xu, H.P., Sun, J.Z., Qin, A.J., 2006. Functional perovskite hybrid of polyacetylene ammonium and lead bromide: synthesis, light emission, and fluorescence imagining. The Journal of Physical Chemistry B, 110(43):21701-21709.

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