CLC number:
On-line Access: 2024-03-13
Received: 2023-05-09
Revision Accepted: 2023-07-12
Crosschecked: 2024-03-13
Cited: 0
Clicked: 843
Jijie YE, Xuan XU, Chuande WU. Synthesis and characterization of three new solid polyoxometalates based on Wells-Dawson-derived sandwich-type polyanions [Co4(H2O)2(P2W15O56)2]16-[J]. Journal of Zhejiang University Science A, 2024, 25(3): 268-274.
@article{title="Synthesis and characterization of three new solid polyoxometalates based on Wells-Dawson-derived sandwich-type polyanions [Co4(H2O)2(P2W15O56)2]16-",
author="Jijie YE, Xuan XU, Chuande WU",
journal="Journal of Zhejiang University Science A",
volume="25",
number="3",
pages="268-274",
year="2024",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A2300250"
}
%0 Journal Article
%T Synthesis and characterization of three new solid polyoxometalates based on Wells-Dawson-derived sandwich-type polyanions [Co4(H2O)2(P2W15O56)2]16-
%A Jijie YE
%A Xuan XU
%A Chuande WU
%J Journal of Zhejiang University SCIENCE A
%V 25
%N 3
%P 268-274
%@ 1673-565X
%D 2024
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A2300250
TY - JOUR
T1 - Synthesis and characterization of three new solid polyoxometalates based on Wells-Dawson-derived sandwich-type polyanions [Co4(H2O)2(P2W15O56)2]16-
A1 - Jijie YE
A1 - Xuan XU
A1 - Chuande WU
J0 - Journal of Zhejiang University Science A
VL - 25
IS - 3
SP - 268
EP - 274
%@ 1673-565X
Y1 - 2024
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.A2300250
Abstract: Three polyoxometalate-based hybrid coordination materials, [Co8(H2O)34(pz)2{Co4(H2O)2P4W30O112}]·16H2O (compound 1), [H3O]4[Co6(H2O)22(pz)2{Co4(H2O)2P4W30O112}]·21H2O (compound 2), and [H3O]4[Co6(H2O)22{Co4(H2O)2P4W30O112}]·29H2O (compound 3) (pz=pyrazine), were built from the linkage of [Co4(H2O)2(P2W15O56)2]16- (abbreviated as {Co4P4W30}) polyanions and pz and/or cobalt(II) cations. Although compounds 1 and 2 consisted of the same components, their lamellar networks were quite different. The inorganic lamellar network in compound 3 was constructed by connecting {Co4P4W30} units with cobalt(II) cations. This work demonstrates that the coordination modes of {Co4P4W30} are very sensitive to synthesis conditions, while the ring-belt tetrametals are easily substituted by different transition metal cations under mild reaction conditions.
[1]AmmamM, MbomekalleIM, KeitaB, et al., 2010. Electrochemical behavior and electrocatalytic properties towards hydrogen peroxide, dioxygen and nitrate of the polyanions [(NiIIOH2)2(FeIII)2(X2W15O56)2]14- (X=PV or AsV): a comparative study. Journal of Electroanalytical Chemistry, 647(2):97-102.
[2]BiLH, ShenY, JiangJG, et al., 2005. Electrochemical behavior and assembly of tetranuclear Dawson-derived sandwich compound [Cd4(H2O)2(As2W15O56)2]16- on 4-aminobenzoic acid modified glassy carbon electrode. Analytica Chimica Acta, 534(2):343-351.
[3]DuDY, QinJS, LiSL, et al., 2014. Recent advances in porous polyoxometalate-based metal-organic framework materials. Chemical Society Reviews, 43(13):4615-4632.
[4]FinkeRG, DroegeMW, DomaillePJ, 1987. Trivacant heteropolytungstate derivatives. 3. Rational syntheses, characterization, two-dimensional 183W NMR, and properties of P2W18M4(H2O)2O6810- and P4W30M4(H2O)2O11216- (M=Co, Cu, Zn). Inorganic Chemistry, 26(23):3886-3896.
[5]Gomez-GarciaCJ, Borras-AlmenarJJ, CoronadoE, et al., 1994. Single-crystal X-ray structure and magnetic properties of the polyoxotungstate complexes Na16[M4(H2O)2(P2W15O56)2]·nH2O (M=MnII, n=53; M=NiII, n=52): an antiferromagnetic MnII tetramer and a ferromagnetic NiII tetramer. Inorganic Chemistry, 33(18):4016-4022.
[6]HarmalkerSP, LeparuloMA, PopeMT, 1983. Mixed-valence chemistry of adjacent vanadium centers in heteropolytungstate anions. 1. Synthesis and electronic structures of mono-, di-, and trisubstituted derivatives of α-[P2W18O62]6-. Journal of the American Chemical Society, 105(13):4286-4292.
[7]KirbyJF, BakerLCW, 1995. Evaluations of a general NMR method, based on properties of heteropoly blues, for determining rates of electron transfer through various bridges. New mixed-mixed valence complexes. Journal of the American Chemical Society, 117(40):10010-10016.
[8]KongXJ, RenYP, ZhengPQ, et al., 2006. Construction of polyoxometalates-based coordination polymers through direct incorporation between polyoxometalates and the voids in a 2D network. Inorganic Chemistry, 45(26):10702-10711.
[9]LiB, ZhaoD, ZhengST, et al., 2008. Hydrothermal synthesis and structural characterization of two organic-inorganic hybrids based on sandwich-type polyoxometalates. Journal of Cluster Science, 19(4):641-650.
[10]LiB, ZhaoD, YangGY, 2009. Hydrothermal synthesis and structural characterization of three one-dimensional heteropolytungstates formed by mono-copperII-substituted Dawson or Keggin cluster units. Journal of Cluster Science, 20(3):629-639.
[11]LiZ, ZhangJH, JingXT, et al., 2021. A polyoxometalate@covalent triazine framework as a robust electrocatalyst for selective benzyl alcohol oxidation coupled with hydrogen production. Journal of Materials Chemistry A, 9(10):6152-6159.
[12]LiaoMY, WangTM, ZuoT, et al., 2021. Design and solvothermal synthesis of polyoxometalate-based Cu(II)-pyrazolate photocatalytic compounds for solar-light-driven hydrogen evolution. Inorganic Chemistry, 60(17):13136-13149.
[13]LiuJX, ZhangXB, LiYL, et al., 2020. Polyoxometalate functionalized architectures. Coordination Chemistry Reviews, 414:213260.
[14]MaPT, HuF, WangJP, et al., 2019. Carboxylate covalently modified polyoxometalates: from synthesis, structural diversity to applications. Coordination Chemistry Reviews, 378:281-309.
[15]MbomekalleIM, KeitaB, NadjoL, et al., 2003a. Lacunary Wells-Dawson sandwich complexes-synthesis, characterization, and stability studies of multi-iron species. European Journal of Inorganic Chemistry, 2003(21):3924-3928.
[16]MbomekalleIM, KeitaB, NadjoL, et al., 2003b. Manganous heteropolytungstates. Synthesis and heteroatom effects in Wells-Dawson-derived sandwich complexes. Dalton Transactions, (13):2646-2650.
[17]MbomekalleIM, CaoR, HardcastleKI, et al., 2005. Synthesis, structural characterization, and electrocatalytic studies of αββα-(ZnIIOH2)2(FeIII)2(X2W15O56)214- (X=P or As). Comptes Rendus Chimie, 8(6-7):1077-1086.
[18]Oxford Diffraction Ltd., 2010. CrysAlisPro, Version 1.171.33.56. Oxford Diffraction Ltd., UK. https://www.agilent.com/cs/library/usermanuals/public/CrysAlis_Pro_User_Manual.pdf
[19]RuhlmannL, CannyJ, ContantR, et al., 2002. Di- and tricobalt Dawson sandwich complexes: synthesis, spectroscopic characterization, and electrochemical behavior of Na18[(NaOH2)2Co2(P2W15O56)2] and Na17[(NaOH2)Co3(H2O)(P2W15O56)2]. Inorganic Chemistry, 41(15):3811-3819.
[20]RuhlmannL, CannyJ, VaissermannJ, et al., 2004. Mixed-metal sandwich complexes [MII2(H2O)2FeIII2(P2W15O56)2]14- (MII=Co, Mn): synthesis and stability. The molecular structure of [MII2(H2O)2FeIII2(P2W15O56)2]14-. Dalton Transactions, (5):794-800.
[21]RuhlmannL, Costa-CoquelardC, CannyJ, et al., 2007. Mixed-metal Dawson sandwich complexes: synthesis, spectroscopic characterization and electrochemical behaviour of Na16[MIICo3(H2O)2(P2W15O56)2] (M=Mn, Co, Ni, Zn and Cd). European Journal of Inorganic Chemistry, 2007(11):1493-1500.
[22]SchamingD, CannyJ, BoubekeurK, et al., 2009. An unprecedented trinuclear Dawson sandwich complex with internal lacuna: synthesis and 31P NMR spectroscopic analysis of the symmetrical [NaNi3(H2O)2(P2W15O56)2]17- and [CoNi3(H2O)2(P2W15O56)2]16- anions. European Journal of Inorganic Chemistry, 2009(33):5004-5009.
[23]SheldrickGM, 1997. SHELXL-97: Program for the Refinement of Crystal Structures. University of Göttingen, Göttingen, Germany.
[24]SongWB, WangXH, LiuY, et al., 1999. Electrochemical and electrocatalytic properties of tetra-iron substituted sandwich-type pentadecatungstodiphosphate heteropolyanions. Journal of Electroanalytical Chemistry, 476(1):85-89.
[25]SpekAL, 2003. Single-crystal structure validation with the program PLATON. Journal of Applied Crystallography, 36(1):7-13.
[26]WangXL, HuHL, TianAX, 2010. Influence of transition metal coordination nature on the assembly of multinuclear subunits in polyoxometalates-based compounds. Crystal Growth & Design, 10(11):4786-4794.
[27]WeakleyTJR, FinkeRG, 1990. Single-crystal X-ray structures of the polyoxotungstate salts K8.3Nal.7[Cu4(H2O)2(PW9O34)2]·24H2O and Na14Cu[Cu4(H2O)2(P2Wl5O56)2]·53H2O. Inorganic Chemistry, 29(6):1235-1241.
[28]YeJJ, WuCD, 2016. Immobilization of polyoxometalates in crystalline solids for highly efficient heterogeneous catalysis. Dalton Transactions, 45(25):10101-10112.
[29]ZhaoHY, LiYZ, ZhaoJW, et al., 2021. State-of-the-art advances in the structural diversities and catalytic applications of polyoxoniobate-based materials. Coordination Chemistry Reviews, 443:213966.
Open peer comments: Debate/Discuss/Question/Opinion
<1>