Full Text:   <634>

Summary:  <198>

Suppl. Mater.: 

CLC number: 

On-line Access: 2024-03-13

Received: 2023-05-09

Revision Accepted: 2023-07-12

Crosschecked: 2024-03-13

Cited: 0

Clicked: 843

Citations:  Bibtex RefMan EndNote GB/T7714

 ORCID:

Chuande WU

https://orcid.org/0000-0001-8128-134X

-   Go to

Article info.
Open peer comments

Journal of Zhejiang University SCIENCE A 2024 Vol.25 No.3 P.268-274

http://doi.org/10.1631/jzus.A2300250


Synthesis and characterization of three new solid polyoxometalates based on Wells-Dawson-derived sandwich-type polyanions [Co4(H2O)2(P2W15O56)2]16-


Author(s):  Jijie YE, Xuan XU, Chuande WU

Affiliation(s):  Department of Chemistry, Zhejiang University, Hangzhou 310058, China

Corresponding email(s):   cdwu@zju.edu.cn

Key Words:  Cobalt, Crystal structure, Cyclic voltammetry, Hybrid, Polyoxometalate


Share this article to: More <<< Previous Article|

Jijie YE, Xuan XU, Chuande WU. Synthesis and characterization of three new solid polyoxometalates based on Wells-Dawson-derived sandwich-type polyanions [Co4(H2O)2(P2W15O56)2]16-[J]. Journal of Zhejiang University Science A, 2024, 25(3): 268-274.

@article{title="Synthesis and characterization of three new solid polyoxometalates based on Wells-Dawson-derived sandwich-type polyanions [Co4(H2O)2(P2W15O56)2]16-",
author="Jijie YE, Xuan XU, Chuande WU",
journal="Journal of Zhejiang University Science A",
volume="25",
number="3",
pages="268-274",
year="2024",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A2300250"
}

%0 Journal Article
%T Synthesis and characterization of three new solid polyoxometalates based on Wells-Dawson-derived sandwich-type polyanions [Co4(H2O)2(P2W15O56)2]16-
%A Jijie YE
%A Xuan XU
%A Chuande WU
%J Journal of Zhejiang University SCIENCE A
%V 25
%N 3
%P 268-274
%@ 1673-565X
%D 2024
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A2300250

TY - JOUR
T1 - Synthesis and characterization of three new solid polyoxometalates based on Wells-Dawson-derived sandwich-type polyanions [Co4(H2O)2(P2W15O56)2]16-
A1 - Jijie YE
A1 - Xuan XU
A1 - Chuande WU
J0 - Journal of Zhejiang University Science A
VL - 25
IS - 3
SP - 268
EP - 274
%@ 1673-565X
Y1 - 2024
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.A2300250


Abstract: 
Three polyoxometalate-based hybrid coordination materials, [Co8(H2O)34(pz)2{Co4(H2O)2P4W30O112}]·16H2O (compound 1), [H3O]4[Co6(H2O)22(pz)2{Co4(H2O)2P4W30O112}]·21H2O (compound 2), and [H3O]4[Co6(H2O)22{Co4(H2O)2P4W30O112}]·29H2O (compound 3) (pz=pyrazine), were built from the linkage of [Co4(H2O)2(P2W15O56)2]16- (abbreviated as {Co4P4W30}) polyanions and pz and/or cobalt(II) cations. Although compounds 1 and 2 consisted of the same components, their lamellar networks were quite different. The inorganic lamellar network in compound 3 was constructed by connecting {Co4P4W30} units with cobalt(II) cations. This work demonstrates that the coordination modes of {Co4P4W30} are very sensitive to synthesis conditions, while the ring-belt tetrametals are easily substituted by different transition metal cations under mild reaction conditions.

制备与表征基于Wells-Dawson三明治型多酸阴离子[Co4(H2O)2(P2W15O56)2]16-的三种新型固态杂多酸材料

作者:叶吉接,胥璇,吴传德
机构:浙江大学,化学系,中国杭州,310058
目的:本文旨在研究Wells-Dawson三明治型杂多酸阴离子[Co4(H2O)2(P2W15O56)2]16-的配位能力、夹心金属离子的稳定性以及氧化还原性质,以拓展有机-无机杂化材料的种类。
创新点:1.首次以Wells-Dawson三明治型杂多酸阴离子[Co4(H2O)2(P2W15O56)2]16-制备了有机-无机杂化材料;2.首次实现在温和条件下取代Wells-Dawson三明治型杂多酸阴离子中的夹心金属离子。
方法:1.在温和条件下合成[Co8(H2O)34(pz)2{Co4(H2O)2P4W30O112}]·16H2O,[H3O]4[Co6(H2O)22(pz)2{Co4(H2O)2P4W30O112}]·21H2O和[H3O]4[Co6(H2O)22{Co4(H2O)2P4W30O112}]·29H2O三种杂多酸固态材料;2.利用X-射线单晶衍射、傅里叶红外谱图、X-射线粉末衍射、热重分析和循环伏安曲线等测试与表征方法对合成的三种杂多酸固态材料进行结构和性质分析。
结论:在温和条件下制备由Wells-Dawson三明治型{Co4P4W30}杂多酸构筑的三种固态配位材料,发现夹心环带中的金属阳离子能够影响杂化材料的骨架结构。此外,首次证明夹心环带中的金属阳离子在相对温和的条件下容易被环境中的过渡金属离子取代。本研究为合理设计和组装具有潜在应用前景的有机-无机杂化材料提供了有益参考。

关键词:钴;晶体结构;循环伏安曲线;杂多酸

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

Reference

[1]AmmamM, MbomekalleIM, KeitaB, et al., 2010. Electrochemical behavior and electrocatalytic properties towards hydrogen peroxide, dioxygen and nitrate of the polyanions [(NiIIOH2)2(FeIII)2(X2W15O56)2]14- (X=PV or AsV): a comparative study. Journal of Electroanalytical Chemistry, 647(2):97-102.

[2]BiLH, ShenY, JiangJG, et al., 2005. Electrochemical behavior and assembly of tetranuclear Dawson-derived sandwich compound [Cd4(H2O)2(As2W15O56)2]16- on 4-aminobenzoic acid modified glassy carbon electrode. Analytica Chimica Acta, 534(2):343-351.

[3]DuDY, QinJS, LiSL, et al., 2014. Recent advances in porous polyoxometalate-based metal-organic framework materials. Chemical Society Reviews, 43(13):4615-4632.

[4]FinkeRG, DroegeMW, DomaillePJ, 1987. Trivacant heteropolytungstate derivatives. 3. Rational syntheses, characterization, two-dimensional 183W NMR, and properties of P2W18M4(H2O)2O6810- and P4W30M4(H2O)2O11216- (M=Co, Cu, Zn). Inorganic Chemistry, 26(23):3886-3896.

[5]Gomez-GarciaCJ, Borras-AlmenarJJ, CoronadoE, et al., 1994. Single-crystal X-ray structure and magnetic properties of the polyoxotungstate complexes Na16[M4(H2O)2(P2W15O56)2]·nH2O (M=MnII, n=53; M=NiII, n=52): an antiferromagnetic MnII tetramer and a ferromagnetic NiII tetramer. Inorganic Chemistry, 33(18):4016-4022.

[6]HarmalkerSP, LeparuloMA, PopeMT, 1983. Mixed-valence chemistry of adjacent vanadium centers in heteropolytungstate anions. 1. Synthesis and electronic structures of mono-, di-, and trisubstituted derivatives of α-[P2W18O62]6-. Journal of the American Chemical Society, 105(13):4286-4292.

[7]KirbyJF, BakerLCW, 1995. Evaluations of a general NMR method, based on properties of heteropoly blues, for determining rates of electron transfer through various bridges. New mixed-mixed valence complexes. Journal of the American Chemical Society, 117(40):10010-10016.

[8]KongXJ, RenYP, ZhengPQ, et al., 2006. Construction of polyoxometalates-based coordination polymers through direct incorporation between polyoxometalates and the voids in a 2D network. Inorganic Chemistry, 45(26):10702-10711.

[9]LiB, ZhaoD, ZhengST, et al., 2008. Hydrothermal synthesis and structural characterization of two organic-inorganic hybrids based on sandwich-type polyoxometalates. Journal of Cluster Science, 19(4):641-650.

[10]LiB, ZhaoD, YangGY, 2009. Hydrothermal synthesis and structural characterization of three one-dimensional heteropolytungstates formed by mono-copperII-substituted Dawson or Keggin cluster units. Journal of Cluster Science, 20(3):629-639.

[11]LiZ, ZhangJH, JingXT, et al., 2021. A polyoxometalate@covalent triazine framework as a robust electrocatalyst for selective benzyl alcohol oxidation coupled with hydrogen production. Journal of Materials Chemistry A, 9(10):6152-6159.

[12]LiaoMY, WangTM, ZuoT, et al., 2021. Design and solvothermal synthesis of polyoxometalate-based Cu(II)-pyrazolate photocatalytic compounds for solar-light-driven hydrogen evolution. Inorganic Chemistry, 60(17):13136-13149.

[13]LiuJX, ZhangXB, LiYL, et al., 2020. Polyoxometalate functionalized architectures. Coordination Chemistry Reviews, 414:213260.

[14]MaPT, HuF, WangJP, et al., 2019. Carboxylate covalently modified polyoxometalates: from synthesis, structural diversity to applications. Coordination Chemistry Reviews, 378:281-309.

[15]MbomekalleIM, KeitaB, NadjoL, et al., 2003a. Lacunary Wells-Dawson sandwich complexes-synthesis, characterization, and stability studies of multi-iron species. European Journal of Inorganic Chemistry, 2003(21):3924-3928.

[16]MbomekalleIM, KeitaB, NadjoL, et al., 2003b. Manganous heteropolytungstates. Synthesis and heteroatom effects in Wells-Dawson-derived sandwich complexes. Dalton Transactions, (13):2646-2650.

[17]MbomekalleIM, CaoR, HardcastleKI, et al., 2005. Synthesis, structural characterization, and electrocatalytic studies of αββα-(ZnIIOH2)2(FeIII)2(X2W15O56)214- (X=P or As). Comptes Rendus Chimie, 8(6-7):1077-1086.

[18]Oxford Diffraction Ltd., 2010. CrysAlisPro, Version 1.171.33.56. Oxford Diffraction Ltd., UK. https://www.agilent.com/cs/library/usermanuals/public/CrysAlis_Pro_User_Manual.pdf

[19]RuhlmannL, CannyJ, ContantR, et al., 2002. Di- and tricobalt Dawson sandwich complexes: synthesis, spectroscopic characterization, and electrochemical behavior of Na18[(NaOH2)2Co2(P2W15O56)2] and Na17[(NaOH2)Co3(H2O)(P2W15O56)2]. Inorganic Chemistry, 41(15):3811-3819.

[20]RuhlmannL, CannyJ, VaissermannJ, et al., 2004. Mixed-metal sandwich complexes [MII2(H2O)2FeIII2(P2W15O56)2]14- (MII=Co, Mn): synthesis and stability. The molecular structure of [MII2(H2O)2FeIII2(P2W15O56)2]14-. Dalton Transactions, (5):794-800.

[21]RuhlmannL, Costa-CoquelardC, CannyJ, et al., 2007. Mixed-metal Dawson sandwich complexes: synthesis, spectroscopic characterization and electrochemical behaviour of Na16[MIICo3(H2O)2(P2W15O56)2] (M=Mn, Co, Ni, Zn and Cd). European Journal of Inorganic Chemistry, 2007(11):1493-1500.

[22]SchamingD, CannyJ, BoubekeurK, et al., 2009. An unprecedented trinuclear Dawson sandwich complex with internal lacuna: synthesis and 31P NMR spectroscopic analysis of the symmetrical [NaNi3(H2O)2(P2W15O56)2]17- and [CoNi3(H2O)2(P2W15O56)2]16- anions. European Journal of Inorganic Chemistry, 2009(33):5004-5009.

[23]SheldrickGM, 1997. SHELXL-97: Program for the Refinement of Crystal Structures. University of Göttingen, Göttingen, Germany.

[24]SongWB, WangXH, LiuY, et al., 1999. Electrochemical and electrocatalytic properties of tetra-iron substituted sandwich-type pentadecatungstodiphosphate heteropolyanions. Journal of Electroanalytical Chemistry, 476(1):85-89.

[25]SpekAL, 2003. Single-crystal structure validation with the program PLATON. Journal of Applied Crystallography, 36(1):7-13.

[26]WangXL, HuHL, TianAX, 2010. Influence of transition metal coordination nature on the assembly of multinuclear subunits in polyoxometalates-based compounds. Crystal Growth & Design, 10(11):4786-4794.

[27]WeakleyTJR, FinkeRG, 1990. Single-crystal X-ray structures of the polyoxotungstate salts K8.3Nal.7[Cu4(H2O)2(PW9O34)2]·24H2O and Na14Cu[Cu4(H2O)2(P2Wl5O56)2]·53H2O. Inorganic Chemistry, 29(6):1235-1241.

[28]YeJJ, WuCD, 2016. Immobilization of polyoxometalates in crystalline solids for highly efficient heterogeneous catalysis. Dalton Transactions, 45(25):10101-10112.

[29]ZhaoHY, LiYZ, ZhaoJW, et al., 2021. State-of-the-art advances in the structural diversities and catalytic applications of polyoxoniobate-based materials. Coordination Chemistry Reviews, 443:213966.

Open peer comments: Debate/Discuss/Question/Opinion

<1>

Please provide your name, email address and a comment





Journal of Zhejiang University-SCIENCE, 38 Zheda Road, Hangzhou 310027, China
Tel: +86-571-87952783; E-mail: cjzhang@zju.edu.cn
Copyright © 2000 - 2024 Journal of Zhejiang University-SCIENCE