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CLC number: O622.6
On-line Access: 2024-08-27
Received: 2023-10-17
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A novel reduction of diketones with i-RMgBr catalyzed by Cp2TiCl2 and deoxygenation of sulfoxides by Cp2TiCl2/Al system
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ZHANG Yong-min, LIN Mao-qin, YU Yong-ping. A novel reduction of diketones with i-RMgBr catalyzed by Cp2TiCl2 and deoxygenation of sulfoxides by Cp2TiCl2/Al system[J]. Journal of Zhejiang University Science A, 2004, 5(10): 1175-1179.
@article{title="A novel reduction of diketones with i-RMgBr catalyzed by Cp2TiCl2 and deoxygenation of sulfoxides by Cp2TiCl2/Al system",
author="ZHANG Yong-min, LIN Mao-qin, YU Yong-ping",
journal="Journal of Zhejiang University Science A",
volume="5",
number="10",
pages="1175-1179",
year="2004",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.2004.1175"
}
%0 Journal Article
%T A novel reduction of diketones with i-RMgBr catalyzed by Cp2TiCl2 and deoxygenation of sulfoxides by Cp2TiCl2/Al system
%A ZHANG Yong-min
%A LIN Mao-qin
%A YU Yong-ping
%J Journal of Zhejiang University SCIENCE A
%V 5
%N 10
%P 1175-1179
%@ 1869-1951
%D 2004
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.2004.1175
TY - JOUR
T1 - A novel reduction of diketones with i-RMgBr catalyzed by Cp2TiCl2 and deoxygenation of sulfoxides by Cp2TiCl2/Al system
A1 - ZHANG Yong-min
A1 - LIN Mao-qin
A1 - YU Yong-ping
J0 - Journal of Zhejiang University Science A
VL - 5
IS - 10
SP - 1175
EP - 1179
%@ 1869-1951
Y1 - 2004
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.2004.1175
Abstract: α-diketone%29&ck%5B%5D=abstract&ck%5B%5D=keyword'>-diketones and β-diketone%29&ck%5B%5D=abstract&ck%5B%5D=keyword'>-diketones react with grignard reagents in the presence of a catalytic amount of Cp2TiCl2 to yield α-ketols and corresponding ketones respectively. Sulfoxides can be deoxygenated by Cp2TiCl2/Al system. The possible mechanisms are also discussed.
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