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Journal of Zhejiang University SCIENCE A 2005 Vol.6 No.7 P.619-622

http://doi.org/10.1631/jzus.2005.A0619


In-situ synthesis and luminescence properties of titanium oxide gels containing 1,10-phenanthroline europium(III) complex


Author(s):  XIE Fei, YANG Hui, XU Cun-jin, ZHANG Xi-he

Affiliation(s):  Institute of Inorganic Nonmetal Materials, School of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China; more

Corresponding email(s):   yanghui@zju.edu.cn

Key Words:  In-situ synthesis, Europium complex, Titanium dioxide gel, Luminescence


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XIE Fei, YANG Hui, XU Cun-jin, ZHANG Xi-he. In-situ synthesis and luminescence properties of titanium oxide gels containing 1,10-phenanthroline europium(III) complex[J]. Journal of Zhejiang University Science A, 2005, 6(7): 619-622.

@article{title="In-situ synthesis and luminescence properties of titanium oxide gels containing 1,10-phenanthroline europium(III) complex",
author="XIE Fei, YANG Hui, XU Cun-jin, ZHANG Xi-he",
journal="Journal of Zhejiang University Science A",
volume="6",
number="7",
pages="619-622",
year="2005",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.2005.A0619"
}

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%T In-situ synthesis and luminescence properties of titanium oxide gels containing 1,10-phenanthroline europium(III) complex
%A XIE Fei
%A YANG Hui
%A XU Cun-jin
%A ZHANG Xi-he
%J Journal of Zhejiang University SCIENCE A
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%@ 1673-565X
%D 2005
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.2005.A0619

TY - JOUR
T1 - In-situ synthesis and luminescence properties of titanium oxide gels containing 1,10-phenanthroline europium(III) complex
A1 - XIE Fei
A1 - YANG Hui
A1 - XU Cun-jin
A1 - ZHANG Xi-he
J0 - Journal of Zhejiang University Science A
VL - 6
IS - 7
SP - 619
EP - 622
%@ 1673-565X
Y1 - 2005
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.2005.A0619


Abstract: 
It is difficult to directly dope europium complexes in gel because the excessive water or high acidic condition may lead to their decomposition. We prepared a novel homogeneous TiO2 gel containing Eu-phen complexes by using an in-situ synthesis method. The formation of Eu-phen complexes in sol-gel derived TiO2 was confirmed by luminescence excitation spectra. The effects of temperature and aging time on in-situ synthesis are discussed. The luminescence spectra of gel containing europium complexes were also compared with the pure Eu-phen complexes.

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

Reference

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[7] Yang, C.M., Wang, S.F., Fang, Z., 1998. A study on IR and fluorescence spectra of solid binary complex compounds of phen-Eu(III) codoped with Y3+ and Gd3+. Chinese J. of Spectroscopy Laboratory, 15(2):10-13 (in Chinese).

[8] Zhang, H.J., Fu, L.S., Wang, S.B., Meng, Q.G, Yang, K.Y., Ni, J.Z., 1999. Luminescence characteristics of europium and terbium complexes with 1,10-phenanthroline in-situ synthesized in a silica matrix by a two-step sol-gel process. Materials Letters, 38:260-264.

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